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Here we introduce a reactant\u2010shunting strategy that installs a guiding electrocatalytic step via isolated Ru atoms to supply surface\u2010bound\n                    <jats:sup>*<\/jats:sup>\n                    H species and enforce a Langmuir\u2013Hinshelwood (LH) hydrogenation pathway. Using Ru\n                    <jats:sub>1<\/jats:sub>\n                    \/Co\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    as a model catalyst, we show that single Ru sites promote water adsorption and dissociation, forming stable Ru\u2010H intermediates that thermodynamically and kinetically accelerate the coupling\u2010hydrogenation steps in NORR. The optimized catalyst delivers an NH\n                    <jats:sub>3<\/jats:sub>\n                    yield of 533.49\u00a0\u00b5mol cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    with a 97.19% faradaic efficiency, surpassing state\u2010of\u2010the\u2010art systems. The reactant\u2010shunting principle further generalizes across multiple oxide hosts, enhancing NH\n                    <jats:sub>3<\/jats:sub>\n                    productivity by up to threefold. These findings establish pathway steering through controlled hydrogen delivery as a powerful strategy for high\u2010efficiency electrocatalytic ammonia synthesis.\n                  <\/jats:p>","DOI":"10.1002\/anie.3369650","type":"journal-article","created":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T08:46:05Z","timestamp":1791621965000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Controlled Hydrogen Delivery by Single\u2010Atom Ru Accelerates Electrocatalytic Ammonia Synthesis"],"prefix":"10.1002","author":[{"given":"Zheng","family":"Liu","sequence":"first","affiliation":[{"name":"International Joint Laboratory of Catalytic Chemistry, State Key Laboratory of Materials for Advanced Nuclear Energy, Innovation Institute of Carbon Neutrality, Department of Chemistry, College of Sciences Shanghai University  Shanghai People's Republic of 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Ludwig\u2010Maximilians\u2010Universit\u00e4t (LMU)  Munich Germany"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-6197-0939","authenticated-orcid":false,"given":"Donglin","family":"Han","sequence":"additional","affiliation":[{"name":"International Joint Laboratory of Catalytic Chemistry, State Key Laboratory of Materials for Advanced Nuclear Energy, Innovation Institute of Carbon Neutrality, Department of Chemistry, College of Sciences Shanghai University  Shanghai People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jialing","family":"Song","sequence":"additional","affiliation":[{"name":"International Joint Laboratory of Catalytic Chemistry, State Key Laboratory of Materials for Advanced Nuclear Energy, Innovation Institute of Carbon Neutrality, Department of Chemistry, College of Sciences Shanghai University  Shanghai People's Republic of 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