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These impurities cause rapid catalyst deactivation, particularly under the high reaction rates required for industrial application. Here, we introduce a hydrophobic molecular gate strategy to decouple impurity transport from catalyst deactivation. By regulating the interfacial water solvation structure and proton transfer pathways, this design creates a water\u2010deficient regime to lock the kinetic switch. As a result, SO\n                    <jats:sub>2<\/jats:sub>\n                    is isolated from the hydrogen\u2010mediated reduction, while the transient water required for efficient CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion is preserved. When paired with a lattice\u2010strained copper catalyst, this architecture allows a scaled\u2010up 100\u00a0cm\n                    <jats:sup>2<\/jats:sup>\n                    membrane electrode assembly (MEA) to operate at a total current of 20 A for over 120 h, maintaining an ethylene (C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>4<\/jats:sub>\n                    ) Faradaic efficiency (FE) &gt;56% in simulated flue gas.\n                  <\/jats:p>","DOI":"10.1002\/anie.3424135","type":"journal-article","created":{"date-parts":[[2026,6,21]],"date-time":"2026-06-21T15:46:19Z","timestamp":1782056779000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Taming the Hydrogen\u2010Mediated Kinetic Switch for Sulfur\u2010Tolerant CO\n                    <sub>2<\/sub>\n                    Electroreduction"],"prefix":"10.1002","volume":"65","author":[{"given":"Mingzhi","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of New Textile Materials and Advanced Processing Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education) Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wensheng","family":"Fang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of New Textile Materials and Advanced Processing Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education) Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lebin","family":"Cai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of New Textile Materials and Advanced Processing Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education) Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Deyu","family":"Zhu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of New Textile Materials and Advanced Processing Key Laboratory of Material Chemistry for Energy Conversion and Storage (Ministry of Education) Hubei Key Laboratory of Material Chemistry and Service Failure School of Chemistry and Chemical Engineering Huazhong University of Science and Technology (HUST)  Wuhan 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