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Herein, we present a dynamic axial Cl coordination strategy to mitigate this issue, realized by precisely engineered O\u2010bridged dual\u2010heteroatom catalysts (FeMn DHACs) for ultrahigh electrochemical ORR activity in seawater. In situ spectroscopy combined with multiscale simulations reveal that one Cl atom dynamically is adsorbed on the Fe site forming a Cl\u2212FeN\n                    <jats:sub>3<\/jats:sub>\n                    \u2212O\n                    <jats:sub>1<\/jats:sub>\n                    \u2212MnN\n                    <jats:sub>3<\/jats:sub>\n                    active structure, which drives the Fe center from D\n                    <jats:sub>4<\/jats:sub>\n                    h to a C\n                    <jats:sub>4<\/jats:sub>\n                    v symmetry and then facilitates *OH dissociation for fast four\u2010electron ORR kinetics. Meanwhile, Mn regulators tailor the adsorption behavior of Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    at Fe sites, suppressing Fe corrosion and enhancing stability. Consequently, this well\u2010designed FeMn DHACs exhibits satisfactory seawater ORR activity with a half\u2010wave potential of 0.941\u00a0V versus RHE and a maximum power density of 179.8\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in a Zn\u2010air battery. Remarkably, it delivers a negligible degradation (only 10\u00a0mV loss) after 30,000 cycles. This enhancement effect is generalizable to other M\u2500Mn (M\u2550Co, Ni, Cu) diatomic systems, demonstrating that Mn sites universally promote the seawater\u2010based ORR route by regulating Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    adsorption.\n                  <\/jats:p>","DOI":"10.1002\/anie.3482426","type":"journal-article","created":{"date-parts":[[2026,9,25]],"date-time":"2026-09-25T04:27:41Z","timestamp":1790310461000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Dynamic\u2010Coupling Axial Chloride on Dual\u2010Heteroatom Sites for Highly Anti\u2010Chloride Oxygen Reduction in Seawater"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-1866-4351","authenticated-orcid":false,"given":"Shiyu","family":"Li","sequence":"first","affiliation":[{"name":"National &amp; Local Joint Engineering Laboratory For New Petro\u2010Chemical Materials and Fine Utilization of Resources College of Chemistry and Chemical Engineering Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education) Hunan Normal University  Changsha P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4370-4038","authenticated-orcid":false,"given":"Zisheng","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering Stanford University  Stanford California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiamei","family":"Pan","sequence":"additional","affiliation":[{"name":"National &amp; Local Joint Engineering Laboratory For New Petro\u2010Chemical Materials and Fine Utilization of Resources College of Chemistry and Chemical Engineering Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education) Hunan Normal University  Changsha P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jin","family":"Yan","sequence":"additional","affiliation":[{"name":"National &amp; Local Joint Engineering Laboratory For New Petro\u2010Chemical Materials and Fine Utilization of Resources College of Chemistry and Chemical Engineering Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education) Hunan Normal University  Changsha P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0263-3026","authenticated-orcid":false,"given":"Haiqing","family":"Zhou","sequence":"additional","affiliation":[{"name":"Key Laboratory for Matter Microstructure and Function of Hunan Province Key Laboratory of Low\u2010Dimensional Quantum Structures and Quantum Control of Ministry of Education Department of Physics and Synergetic innovation Center for Quantum Effects and Applications Hunan Normal University  Changsha P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9393-7123","authenticated-orcid":false,"given":"Xiongwei","family":"Wu","sequence":"additional","affiliation":[{"name":"National &amp; Local Joint Engineering Laboratory For New Petro\u2010Chemical Materials and Fine Utilization of Resources College of Chemistry and Chemical Engineering Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education) Hunan Normal University  Changsha P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7653-3426","authenticated-orcid":false,"given":"Hui","family":"Su","sequence":"additional","affiliation":[{"name":"National &amp; Local Joint Engineering Laboratory For New Petro\u2010Chemical Materials and Fine Utilization of Resources College of Chemistry and Chemical Engineering Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research (Ministry of Education) Hunan Normal University  Changsha P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,24]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202508141"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202405763"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010026\u201001482\u20102"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010025\u201009364\u20106"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D0EE01617A"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202405852"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE04619F"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c04206"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.2c11844"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202518307"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201047121\u2010x"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202504872"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202422874"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202509911"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202504923"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010021\u201001030\u20102"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202524529"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE01309C"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c06463"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201066362\u2010y"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202302251"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010023\u201001195\u2010x"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202420615"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c06434"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423556"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.157940"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010021\u201000878\u20107"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010023\u201001062\u20108"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c17444"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.9b01617"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010022\u201029357\u20107"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202509360"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010024\u201000545\u20101"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202511844"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202412598"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apsusc.2022.154384"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c18264"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtphys.2025.101739"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202500500"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202502834"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mtcata.2024.100068"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.1c01316"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE00823E"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202424135"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202505268"}],"container-title":["Angewandte 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