{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,7]],"date-time":"2026-10-07T13:03:10Z","timestamp":1791378190891,"version":"4.3.2"},"reference-count":83,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T00:00:00Z","timestamp":1790467200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Transition\u2010metal incorporation is widely employed to enhance the photoelectrochemical performance of BiVO\n                    <jats:sub>4<\/jats:sub>\n                    photoanodes, yet how the local incorporation environment governs charge\u2010carrier dynamics remains poorly understood. Here, we establish a structure\u2010function relationship between the local environments of Fe, Co, and Ni and the resulting charge\u2010dynamics in BiVO\n                    <jats:sub>4<\/jats:sub>\n                    . Combining synchrotron\u2010based x\u2010ray spectroscopies with femtosecond\u2010to\u2010microsecond photophysical measurements, we show that all transition metals improve water oxidation activity relative to pristine BiVO\n                    <jats:sub>4<\/jats:sub>\n                    , following the trend (Ni &gt; Fe &gt; Co) &gt; BiVO\n                    <jats:sub>4<\/jats:sub>\n                    . Fe and Co predominantly adopt heterogeneous, oxide\u2010like local environments associated with weaker and more spatially heterogeneous coupling to the BiVO\n                    <jats:sub>4<\/jats:sub>\n                    framework, resulting in moderate improvements in charge separation. In contrast, Ni forms highly oxidized, locally octahedrally coordinated Ni\u2013O units that exhibit stronger electronic coupling with the BiVO\n                    <jats:sub>4<\/jats:sub>\n                    framework, modifying the V\u2013O electronic structure, suppressing charge localization and recombination, and extending carrier lifetimes across multiple timescales.\n                    <jats:italic>Operando<\/jats:italic>\n                    x\u2010ray absorption further reveals that incorporated Ni species remain electronically responsive under working conditions, linking their local electronic structure to photogenerated charge accumulation. These findings demonstrate that the photoelectrochemical behavior of transition\u2010metal\u2010modified BiVO\n                    <jats:sub>4<\/jats:sub>\n                    is governed by the nature of metal\u2013host electronic coupling rather than metal identity alone, providing a general design principle for oxide photoanodes.\n                  <\/jats:p>","DOI":"10.1002\/anie.3499350","type":"journal-article","created":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T16:37:32Z","timestamp":1790527052000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Local Coordination and Electronic Coupling Governs Charge Dynamics in BiVO\n                    <sub>4<\/sub>\n                    Photoanodes"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4381-3787","authenticated-orcid":false,"given":"Alejandro","family":"Garc\u00eda\u2010Eguiz\u00e1bal","sequence":"first","affiliation":[{"name":"Photoactivated Processes Unit, IMDEA Energy Institute, Parque Tecnol\u00f3gico De M\u00f3stoles Avda. Ram\u00f3n de La Sagra 3  M\u00f3stoles Madrid Spain"},{"name":"Present Address: Departamento de Qu\u00edmica, Instituto de Qu\u00edmica de La Universidad de La Rioja Universidad De La Rioja, C\/Madre De Dios 53  Logro\u00f1o Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8450-2563","authenticated-orcid":false,"given":"Camilo A.","family":"Mesa","sequence":"additional","affiliation":[{"name":"Catalan Institute of Nanoscience and Nanotechnology (ICN2), CSIC and Barcelona Institute of Science and Technology (BIST) Campus UAB  Bellaterra Barcelona Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mariam","family":"Barawi","sequence":"additional","affiliation":[{"name":"Photoactivated Processes Unit, IMDEA Energy Institute, Parque Tecnol\u00f3gico De M\u00f3stoles Avda. Ram\u00f3n de La Sagra 3  M\u00f3stoles Madrid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6370-9998","authenticated-orcid":false,"given":"Miguel","family":"Gomez\u2010Mendoza","sequence":"additional","affiliation":[{"name":"Photoactivated Processes Unit, IMDEA Energy Institute, Parque Tecnol\u00f3gico De M\u00f3stoles Avda. Ram\u00f3n de La Sagra 3  M\u00f3stoles Madrid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ignacio J.","family":"Villar\u2010Garc\u00eda","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biochemistry, Facultad de Farmacia Universidad San Pablo\u2010CEU, CEU Universities  Boadilla del Monte Madrid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5759-9980","authenticated-orcid":false,"given":"Felipe A.","family":"Garc\u00e9s\u2010Pineda","sequence":"additional","affiliation":[{"name":"Institute of Chemical Research of Catalonia (ICIQ\u2010CERCA) The Barcelona Institute of Science and Technology (BIST), Av. Pa\u00efsos Catalans 16  Tarragona Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2430-4458","authenticated-orcid":false,"given":"Soranyel","family":"Gonzalez\u2010Carrero","sequence":"additional","affiliation":[{"name":"Department of Chemistry Imperial College London  London UK"},{"name":"Present Address: Institute of Molecular Science University of Valencia  Paterna Valencia Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alejandro","family":"Garc\u00eda\u2010Ca\u00f1as","sequence":"additional","affiliation":[{"name":"Photoactivated Processes Unit, IMDEA Energy Institute, Parque Tecnol\u00f3gico De M\u00f3stoles Avda. Ram\u00f3n de La Sagra 3  M\u00f3stoles Madrid Spain"},{"name":"Present Address: Grupo de L\u00e1minas Delgadas e Iones de Alta Energ\u00eda (GOLD\u2010FOTION) Instituto De \u00d3ptica (CSIC). Calle Serrano, 144  Madrid Spain"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8353-7345","authenticated-orcid":false,"given":"James R.","family":"Durrant","sequence":"additional","affiliation":[{"name":"Department of Chemistry Imperial College London  London UK"},{"name":"Present Address: Chemistry Research Laboratory University of Oxford  Oxford UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1724-1586","authenticated-orcid":false,"given":"Marta","family":"Liras","sequence":"additional","affiliation":[{"name":"Photoactivated Processes Unit, IMDEA Energy Institute, Parque Tecnol\u00f3gico De M\u00f3stoles Avda. 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