{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T18:55:42Z","timestamp":1791226542893,"version":"4.1.0"},"reference-count":51,"publisher":"Wiley","issue":"41","license":[{"start":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T00:00:00Z","timestamp":1786492800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T00:00:00Z","timestamp":1786492800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/100009035","name":"Academic Senate, University of California, Riverside","doi-asserted-by":"publisher","id":[{"id":"10.13039\/100009035","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001691","name":"Japan Society for the Promotion of Science","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100001691","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,10,5]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Multifunctional materials are critically important for modern technologies. Magnets, especially those relevant to spintronic applications, are essential for energy\u2010efficient data processing and advanced magnetic devices, while high\u2010strength materials provide excellent mechanical and thermal stability. Mo\n                    <jats:sub>2<\/jats:sub>\n                    FeB\n                    <jats:sub>2<\/jats:sub>\n                    \u2010type materials are well established for their superior strength and thermal properties, yet their magnetic behavior has remained largely theoretical, dominated by antiferromagnets and, more recently, predicted altermagnets. Building on our recent report of spin\u2010glass phases exhibiting large anisotropy, we have discovered Mo\n                    <jats:sub>2<\/jats:sub>\n                    FeB\n                    <jats:sub>2<\/jats:sub>\n                    \u2010type high\u2010temperature ferromagnets: Mn\u2010rich MoMn\n                    <jats:sub>2<\/jats:sub>\n                    B\n                    <jats:sub>2<\/jats:sub>\n                    and WMn\n                    <jats:sub>2<\/jats:sub>\n                    B\n                    <jats:sub>2<\/jats:sub>\n                    . These compounds exhibit magnetic ordering above room temperature, with Curie temperatures (and Weiss constants) of 400 K (\n                    <jats:italic>\u03b8<\/jats:italic>\n                    \u00a0=\u00a0229 K) and 380 K (\n                    <jats:italic>\u03b8<\/jats:italic>\n                    \u00a0=\u00a0+154 K), respectively. Notably, rare\u2010earth\u2010free WMn\n                    <jats:sub>2<\/jats:sub>\n                    B\n                    <jats:sub>2<\/jats:sub>\n                    displays enhanced coercivity with an intrinsic coercivity of 67.6 kA\u00a0m\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 5\u00a0K, supported by DFT calculations revealing a large in\u2010plane magnetocrystalline anisotropy energy of +0.27\u00a0meV\/f.u., driven by the strong spin\u2010orbit coupling of tungsten. These findings show that Mn\u2010rich Mo\n                    <jats:sub>2<\/jats:sub>\n                    FeB\n                    <jats:sub>2<\/jats:sub>\n                    \u2010type borides are promising rare\u2010earth\u2010free permanent magnet candidates that combine high\u2010temperature ferromagnetism, enhanced magnetic anisotropy, and excellent structural stability.\n                  <\/jats:p>","DOI":"10.1002\/anie.3669169","type":"journal-article","created":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T16:45:06Z","timestamp":1786553106000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Anisotropy\u2010Driven Discovery of Rare\u2010Earth\u2010Free Magnets in Mo\n                    <sub>2<\/sub>\n                    FeB\n                    <sub>2<\/sub>\n                    \u2010Type Borides"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7750-8174","authenticated-orcid":false,"given":"Shola E.","family":"Adeniji","sequence":"first","affiliation":[{"name":"Department of Chemistry University of California  Riverside California USA"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9031-2355","authenticated-orcid":false,"given":"Alexei A.","family":"Belik","sequence":"additional","affiliation":[{"name":"Research Center for Materials Nanoarchitectonics (MANA) National Institute for Materials Science (NIMS)  Tsukuba Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6796-0773","authenticated-orcid":false,"given":"Akira","family":"Yasuhara","sequence":"additional","affiliation":[{"name":"JEOL Ltd  Akishima Tokyo Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kunio","family":"Yubuta","sequence":"additional","affiliation":[{"name":"Institute For Aqua Regeneration (ARG) Shinshu University  Nagano Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2682-1846","authenticated-orcid":false,"given":"Takao","family":"Mori","sequence":"additional","affiliation":[{"name":"Research Center for Materials Nanoarchitectonics (MANA) National Institute for Materials Science (NIMS)  Tsukuba Japan"},{"name":"Graduate School of Pure and Applied Sciences University of Tsukuba  Tsukuba Japan"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9802-7815","authenticated-orcid":false,"given":"Boniface P. 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