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In this field, the development of efficient photocatalysts plays a crucial role. Conventional ruthenium and iridium polypyridyl photocatalysts are limited by the expense of these precious metals. From a sustainable perspective, organic photocatalysts represent cost\u2010effective and mild alternatives to photoredox catalysis; however, tuning their redox properties often requires complicated synthetic approach. Here we introduce N\u2010heterocyclic carbene\u2010triarylamine hybrids as novel donor\u2013acceptor\u2010type organophotocatalysts. These hybrids feature with facile structural modification, broad intramolecular charge\u2010transfer absorption bands, and tunable redox potentials. Furthermore, these new photocatalysts have been successfully utilized for five distinct visible\u2010light\u2010induced redox\u2010neutral radical cross\u2010coupling reactions (94 examples, up to 99% yield). Mechanistic studies indicate that visible\u2010light irradiation of the photocatalyst generates a charge\u2010shifted excited state through photoinduced intramolecular electron transfer. This finding has a guiding significance for the design and development of new organophotocatalysts.<\/jats:p>","DOI":"10.1002\/anie.3699223","type":"journal-article","created":{"date-parts":[[2026,10,6]],"date-time":"2026-10-06T03:12:00Z","timestamp":1791256320000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["N\u2010Heterocyclic Carbene\u2010Triarylamine Hybrids as Redox\u2010Tunable Organophotocatalysts for Radical Cross\u2010Coupling Reactions"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1122-4806","authenticated-orcid":false,"given":"Wei","family":"Ding","sequence":"first","affiliation":[{"name":"College of Chemistry, Henan Institute of Advanced Technology Zhengzhou University  Zhengzhou P. R. 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