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Although oxyanion incorporation can mitigate Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    poisoning, existing approaches offer limited control over oxyanion generation and retention during catalyst reconstruction. Herein, we report a MOF\u2010based ligand\u2010engineering strategy that enables defined oxyanion incorporation into reconstructed metal oxyhydroxides for active and durable seawater electrolysis. Nitro\u2010 (NO\n                    <jats:sub>2<\/jats:sub>\n                    ) functionalized ligands are incorporated into a NiFe\u2010MOF precursor, where the NO\n                    <jats:sub>2<\/jats:sub>\n                    group undergo a simple and direct oxidation to nitrate (NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    ) during electrochemical reconstruction, enabling well\u2010defined NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    regulation of the reconstructed \u03b3\u2010NiFeOOH phase. The anchored NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    not only forms a robust Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    \u2010repelling interface but also activates lattice oxygen to drive a mechanistic transition from an adsorbate evolution mechanism to a more efficient lattice\u2010oxygen\u2010mediated pathway. The designed catalyst achieves excellent oxygen evolution reaction performance in alkaline seawater, requiring an overpotential of only 230\u00a0mV to reach a current density of 500\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    , outperforming its NO\n                    <jats:sub>3<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    \u2010free counterpart. It also exhibits high durability, operating for over 4000 h at 1.5 A cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    with an ultralow degradation rate of 1.8 \u00b5V h\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Furthermore, a kilowatt\u2010level alkaline seawater electrolyzer equipped with the designed electrode operates stably for over 1100 h under industrially relevant conditions.\n                  <\/jats:p>","DOI":"10.1002\/anie.3751410","type":"journal-article","created":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T03:07:26Z","timestamp":1789528046000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Ligand\u2010Directed Nitrate Incorporation Into Reconstructed Oxyhydroxides for Durable Seawater Electrolysis"],"prefix":"10.1002","author":[{"given":"Huangcong","family":"Tang","sequence":"first","affiliation":[{"name":"Guangdong Provincial Key Laboratory of Fuel Cell Technology School of Chemistry and Chemical Engineering South China University of Technology  Guangzhou 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