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Herein, we report the first C\u2500S bond formation of aryl germanes. In contrast to conventional C\u2500S cross\u2010couplings of prefunctionalized arenes that largely rely on transition\u2010metal catalysis, this transformation proceeds in the absence of a metal catalyst at room temperature and tolerates air and moisture. The reaction is orthogonal to common coupling handles, including aryl halides and aryl silanes, enabling selective thiolations in multifunctional molecules. 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