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However, the catalytic activity and selectivity of this reaction still need to be improved for practical applications. Herein, we reveal that a highly active, selective, and stable electroreduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    to formic acid could be realized by wrapping tin sulfide (SnS\n                    <jats:sub>x<\/jats:sub>\n                    ) nanoparticles with graphene oxide (GO) nanosheets. The GO wrapping helps to preserve the crystal size of SnS\n                    <jats:sub>x<\/jats:sub>\n                    (2\u223c4\u00a0nm) and confine the sulfur atoms in SnS\n                    <jats:sub>x<\/jats:sub>\n                    , obtaining a promising catalyst. As a result, a high current density of 126.25 \u00b1 0.78\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and high Faradaic efficiency (FE) of 99.9 \u00b1 1.1% toward formic acid is achieved in a flow cell. The current density could be further improved to 554.41 \u00b1 2.32\u00a0mA cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    in a membrane electrolyzer. Additionally, our catalytic system demonstrates a high stability exceeding 50\u00a0h at ampere\u2010level current. This finding provides a valuable insight for further development of highly efficient and selective catalysts for electroreduction of CO\n                    <jats:sub>2<\/jats:sub>\n                    to high\u2010value carbon\u2010containing products. Our strategy may also be applied to preserve the structures of many other amorphous or nanocrystal catalysts for efficient and stable electrocatalysis.\n                  <\/jats:p>","DOI":"10.1002\/anie.3823676","type":"journal-article","created":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T07:19:13Z","timestamp":1773040753000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Wrapping Tin Sulfide Nanocatalysts with Graphene Oxide Nanosheets for Improved Electroreduction of Carbon Dioxide to Formic Acid"],"prefix":"10.1002","volume":"65","author":[{"given":"Haonan","family":"Chen","sequence":"first","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute ofadvanced Materials (IAM) School of Flexible Electronics (FutureTechnologies) Nanjing Tech University (NanjingTech)  Nanjing Jiangsu China"},{"name":"School of Pharmaceutical and Chemical Engineering Zhejiang Key Laboratory For Island Green Energy and New Materials Taizhou University  Jiaojiang Zhejiang P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xinya","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute ofadvanced Materials (IAM) School of Flexible Electronics (FutureTechnologies) Nanjing Tech University (NanjingTech)  Nanjing Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qinghua","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute ofadvanced Materials (IAM) School of Flexible Electronics (FutureTechnologies) Nanjing Tech University (NanjingTech)  Nanjing Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhiwei","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute ofadvanced Materials (IAM) School of Flexible Electronics (FutureTechnologies) Nanjing Tech University (NanjingTech)  Nanjing Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yaning","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute ofadvanced Materials (IAM) School of Flexible Electronics (FutureTechnologies) Nanjing Tech University (NanjingTech)  Nanjing Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lu","family":"Jiang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute ofadvanced Materials (IAM) School of Flexible Electronics (FutureTechnologies) Nanjing Tech University (NanjingTech)  Nanjing Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Miao","family":"Ji","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute ofadvanced Materials (IAM) School of Flexible Electronics (FutureTechnologies) Nanjing Tech University (NanjingTech)  Nanjing Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0106-7763","authenticated-orcid":false,"given":"Xiao","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Flexible Electronics (LoFE) &amp; Institute ofadvanced Materials (IAM) School of Flexible Electronics (FutureTechnologies) Nanjing Tech University (NanjingTech)  Nanjing Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4567-4976","authenticated-orcid":false,"given":"Gongqiang","family":"Li","sequence":"additional","affiliation":[{"name":"School of Pharmaceutical and Chemical Engineering Zhejiang Key Laboratory For Island Green Energy and New Materials Taizhou University  Jiaojiang Zhejiang P.R. 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