{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T09:08:22Z","timestamp":1789031302445,"version":"build-2803163510"},"reference-count":64,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T00:00:00Z","timestamp":1788998400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T00:00:00Z","timestamp":1788998400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100004329","name":"Javna Agencija za Raziskovalno Dejavnost RS","doi-asserted-by":"publisher","award":["P2\u20100118"],"award-info":[{"award-number":["P2\u20100118"]}],"id":[{"id":"10.13039\/501100004329","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Control over crystallographic orientation in metal\u2010organic framework (MOF) thin films is crucial for exploiting their anisotropic properties in sensing, catalysis, and separation. Achieving reproducible, highly oriented films remains challenging, especially for mixed\u2010linker, pillared\u2010layered frameworks. Here we present an automated, spin\u2010assisted layer\u2010by\u2010layer liquid\u2010phase epitaxy (LbL\u2010LPE) strategy that enables rapid, ambient\u2010condition fabrication of highly oriented, mixed\u2010linker MOF thin films, demonstrated for Zn\n                    <jats:sub>2<\/jats:sub>\n                    BDC\n                    <jats:sub>2<\/jats:sub>\n                    DABCO (BDC\u00a0=\u00a0terephthalate, DABCO = 1,4\u2010diazabicyclo[2.2.2]octane). Correlative process monitoring by grazing\u2010incidence wide\u2010angle x\u2010ray scattering (GIWAXS), grazing\u2010angle infrared (GI\u2010IR) and UV\u2010Vis spectroscopy, contact\u2010angle measurements, scanning electron microscopy (SEM), and time\u2010of\u2010flight secondary ion mass spectrometry (ToF\u2010SIMS) ensures formation of uniform films with exceptional out\u2010of\u2010plane (001) orientation (degree of orientation &gt; 85%, Hermans orientation parameter \u223c0.95) and excellent reproducibility. This strategy enables high\u2010throughput fabrication of orientation\u2010controlled MOF thin films, providing a generalizable alternative to conventional LbL approaches. The resulting highly oriented Zn\n                    <jats:sub>2<\/jats:sub>\n                    (BDC)\n                    <jats:sub>2<\/jats:sub>\n                    (DABCO) thin films retain their crystallinity after prolonged exposure to 80% and short\u2010term exposure up to 90% relative humidity, whereas defect\u2010rich films undergo rapid degradation. Thus, this reproducible, automated strategy establishes the role of crystallographic orientation in humidity stability and advances the integration of oriented MOFs into optoelectronic, sensing, and membrane devices.\n                  <\/jats:p>","DOI":"10.1002\/anie.3901165","type":"journal-article","created":{"date-parts":[[2026,9,10]],"date-time":"2026-09-10T08:29:53Z","timestamp":1789028993000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Automated Spin\u2010Assisted Layer\u2010by\u2010Layer Epitaxy Produces Highly Oriented Mixed\u2010Linker MOF Thin Films"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0434-1753","authenticated-orcid":false,"given":"Eleonora","family":"Afanasenko","sequence":"first","affiliation":[{"name":"CERIC\u2010ERIC  Trieste 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