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Here, we establish latent solvation chemistry to construct a dynamically evolving solvation environment in which a suitably selected diluent remains weakly coordinated at room temperature but is recruited into the Li\n                    <jats:sup>+<\/jats:sup>\n                    solvation shell upon cooling. Guided by lithiophilicity and electrostatic stickiness, we identify a diluent that combines temperature\u2010activated Li\n                    <jats:sup>+<\/jats:sup>\n                    coordination with favorable transport characteristics. Upon cooling, its recruitment into the Li\n                    <jats:sup>+<\/jats:sup>\n                    solvation shell reorganizes the solvation environment, facilitating ion transport and interfacial charge transfer. The resulting electrolyte also forms a thin, LiF\u2010rich interphase that supports efficient low\u2010temperature Li\n                    <jats:sup>+<\/jats:sup>\n                    transport. The designed electrolyte enables 5 C fast charging at \u221220\u00b0C and stable cycling at \u221250\u00b0C with a reversible capacity above 150\u00a0mAh\u00a0g\n                    <jats:sup>\u2212<\/jats:sup>\n                    <jats:sup>1<\/jats:sup>\n                    . A 1.2\u00a0Ah pouch cell retains 91.04% of its initial capacity after 2000 cycles over more than 600 days. This work establishes latent solvation chemistry as a molecular design strategy for wide\u2010temperature fast charging in lithium\u2010ion batteries.\n                  <\/jats:p>","DOI":"10.1002\/anie.3947346","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T06:06:42Z","timestamp":1790748402000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Latent Solvation Chemistry with Low Electrostatic Stickiness Enables Wide\u2010Temperature Fast\u2010Charging Lithium\u2010Ion Batteries"],"prefix":"10.1002","author":[{"given":"Liang","family":"Li","sequence":"first","affiliation":[{"name":"Hefei National Research Center for Physical Sciences at the Microscale CAS Key Laboratory of Materials for Energy Conversion Department of Materials Science and Engineering University of Science and Technology of China Hefei Anhui 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