{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T15:53:58Z","timestamp":1791647638608,"version":"4.3.4"},"reference-count":69,"publisher":"Wiley","issue":"42","license":[{"start":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T00:00:00Z","timestamp":1787529600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T00:00:00Z","timestamp":1787529600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,10,12]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    A layer\u2010type host, an interlayer adaptive crystal (LAC) constructed from paddle\u2010wheel Zn(II) nodes, tetrafluoroisophthalate (\n                    <jats:italic>L<\/jats:italic>\n                    ) linkers, and pyridine (Py) axial ligands, [Zn(\n                    <jats:italic>L<\/jats:italic>\n                    )Py]\n                    <jats:sub>2n<\/jats:sub>\n                    , exhibits guest\u2010induced, electrostatically driven breathing. The crystal contains 2.6 \u00c5 \u03c0\u2010hole\u2010defined ultramicropores that act not as classical channels but as electrostatic triggers for guest\u2010induced single\u2010crystal\u2010to\u2010single\u2010crystal expansion. Dynamic modulation of interlayer spacing and surface contacts yields exceptional flexibility and molecular selectivity. Tetrafluorophenyl \u03c0\u2010holes generate positive quadrupole fields that drive adsorption through host\u2013host repulsion and strong recognition of guests with negative quadrupole moments. Uniaxial voids occupy 12% of the volume, allowing uptake of molecules larger than the ultramicropore. N\n                    <jats:sub>2<\/jats:sub>\n                    , CO\n                    <jats:sub>2<\/jats:sub>\n                    , CH\n                    <jats:sub>4<\/jats:sub>\n                    , and benzene show type\u2010I adsorption from very low pressure, incorporating 1.2, 2.0, 1.5, and 1.0 molecules per [Zn(\n                    <jats:italic>L<\/jats:italic>\n                    )Py]\n                    <jats:sub>2<\/jats:sub>\n                    unit. CO\n                    <jats:sub>2<\/jats:sub>\n                    uptake is accompanied by fully reversible interlayer expansion, while benzene inclusion expands the void space to 186% of that of the guest\u2010free crystal. CO\n                    <jats:sub>2<\/jats:sub>\n                    is preferentially adsorbed over N\n                    <jats:sub>2<\/jats:sub>\n                    and CH\n                    <jats:sub>4<\/jats:sub>\n                    , corroborated by recognition trends among benzene, trifluorobenzene, and hexafluorobenzene. Guest molecules form one\u2010dimensional arrays within the expanded lattice, and the breathing two\u2010dimensional sheet combines the uptake capability of metal\u2010organic frameworks (MOFs) with the molecular precision of nonporous adaptive crystals (NACs), demonstrating an interaction\u2010programmed mode of selective molecular inclusion.\n                  <\/jats:p>","DOI":"10.1002\/anie.4090353","type":"journal-article","created":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T16:28:26Z","timestamp":1787588906000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Low\u2010Pressure CO\n                    <sub>2<\/sub>\n                    and Aromatic Recognition by Interlayer Adaptive Crystal of \u03c0\u2010Hole\u2010Functionalized Zn(II) Coordination Sheets"],"prefix":"10.1002","volume":"65","author":[{"given":"Masahiro","family":"Abe","sequence":"first","affiliation":[{"name":"Department of Applied 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