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Here, we demonstrate a charge\u2010directed photothermal DRM catalyst composed of Rh nanoparticles supported on TiO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    \u2010functionalized TiC, where interfacial TiO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    domains play a critical role by coupling directional photocarrier flow with adaptive oxygen chemistry. Upon illumination, metallic TiC generates charge carriers that transfer electrons to Rh sites while steering holes to TiO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    surface oxygens. This charge\u2010directed interfacial chemistry selectively lowers the barrier for *OCH\n                    <jats:sub>3<\/jats:sub>\n                    formation, the potential\u2010determining step, thus suppressing *CH\n                    <jats:sub>3<\/jats:sub>\n                    over\u2010dehydrogenation and mitigating carbon formation. Concurrently, CO\n                    <jats:sub>2<\/jats:sub>\n                    activation at oxygen vacancies within TiO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    regions restocks surface oxygens, closing a regenerative photothermal Mars\u2013van Krevelen cycle. As a result, the catalyst delivers high syngas production rates (CO: 17.5\u00a0mol g\n                    <jats:sub>Rh<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , H\n                    <jats:sub>2<\/jats:sub>\n                    : 10.5\u00a0mol g\n                    <jats:sub>Rh<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    ), attains a light\u2010to\u2010chemical energy efficiency of 29%, and operates stably for over 100\u00a0h without coking. This work highlights the mechanistic importance of amorphous TiO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    interface in charge\u2010directed photothermal DRM and provides design insights for developing coking\u2010resistant reforming catalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.4126002","type":"journal-article","created":{"date-parts":[[2026,6,13]],"date-time":"2026-06-13T16:59:56Z","timestamp":1781369996000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Charge\u2010Directed Photothermal Methane Dry Reforming Enabled by Interfacial TiO\n                    <i>\n                      <sub>x<\/sub>\n                    <\/i>\n                    Nanodomains"],"prefix":"10.1002","volume":"65","author":[{"given":"Bifang","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemistry for NBC Hazards Protection, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Li","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry for NBC Hazards Protection, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Bo","family":"Su","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry for NBC Hazards Protection, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiabin","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry for NBC Hazards Protection, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kunlong","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry for NBC Hazards Protection, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7437-1088","authenticated-orcid":false,"given":"Chengyang","family":"Feng","sequence":"additional","affiliation":[{"name":"Center For Renewable Energy and Storage Technologies (CREST), Physical Science and Engineering Division King Abdullah University of Science and Technology (KAUST)  Thuwal Kingdom of Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiahui","family":"Lin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry for NBC Hazards Protection, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6983-3700","authenticated-orcid":false,"given":"Yidong","family":"Hou","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry for NBC Hazards Protection, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1601-2471","authenticated-orcid":false,"given":"Huabin","family":"Zhang","sequence":"additional","affiliation":[{"name":"Center For Renewable Energy and Storage Technologies (CREST), Physical Science and Engineering Division King Abdullah University of Science and Technology (KAUST)  Thuwal Kingdom of Saudi Arabia"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2656-9169","authenticated-orcid":false,"given":"Sibo","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry for NBC Hazards Protection, State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry Fuzhou University  Fuzhou 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