{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T08:01:06Z","timestamp":1790841666222,"version":"4.1.0"},"reference-count":41,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T00:00:00Z","timestamp":1790812800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T00:00:00Z","timestamp":1790812800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100004204","name":"Tongji University","doi-asserted-by":"publisher","id":[{"id":"10.13039\/501100004204","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Ether\u2010based electrolytes exhibit excellent anode compatibility and fast ion kinetics, yet their practical application is hindered by continuous cathode interfacial decomposition due to low oxidation resistance. Traditional solvation\u2010regulation strategies face a trade\u2010off between stabilizing the interface and maintaining bulk ion transport, making synergistic optimization challenging. Herein, we propose an in situ solvent polymerization strategy to develop a liquid polymer electrolyte (NEDL) that concurrently achieves fast ion transport and high interfacial stability. Specifically, trace LiPF\n                    <jats:sub>6<\/jats:sub>\n                    initiates the partial ring\u2010opening polymerization of 1,3\u2010dioxolane (DOL) in diethylene glycol dimethyl ether (DEGDME), generating PDOL with abundant coordination sites to reconstruct the Na\n                    <jats:sup>+<\/jats:sup>\n                    solvation structure. This polymer\u2010modulated environment lowers the Na\n                    <jats:sup>+<\/jats:sup>\n                    desolvation energy barrier, accelerating interfacial kinetics, and drives the formation of an inorganic\u2010enriched, robust interphase that suppresses solvent decomposition. Consequently, under a 16\u00a0mg cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    mass loading, the Na\n                    <jats:sub>3<\/jats:sub>\n                    Fe\n                    <jats:sub>2<\/jats:sub>\n                    (PO\n                    <jats:sub>4<\/jats:sub>\n                    )P\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>7<\/jats:sub>\n                    (NFPP)||Na coin cell delivers 94.76% capacity retention after 500 cycles at 2 C. Moreover, practical NFPP||hard carbon (HC) pouch cells retain 96.59% capacity over 500 cycles at 0.5 C. This work provides fundamental insights into how polymer\u2010chain solvation behavior regulates ion transport kinetics and interfacial properties, offering a viable pathway for designing high\u2010performance sodium\u2010ion battery electrolytes.\n                  <\/jats:p>","DOI":"10.1002\/anie.4157238","type":"journal-article","created":{"date-parts":[[2026,10,1]],"date-time":"2026-10-01T07:35:09Z","timestamp":1790840109000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Reconfiguring Electrolyte Solvation Chemistry via In Situ Solvent Polymerization for High\u2010Performance Sodium\u2010Ion Batteries"],"prefix":"10.1002","author":[{"given":"Enmin","family":"Li","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Key Laboratory of Advanced Civil Engineering Materials of Ministry of Education Tongji University  Shanghai 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