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However, most reported systems exhibit single\u2010mode emission, operating either in crystalline forms (typically small\u2010molecule matrices) or in amorphous states (often polymer\u2010based). Herein, we employ 1,2,3,4\u2010butanetetracarboxylic acid (BTA) as the host matrix and construct a series of doped materials by incorporating nine benzofuran[2,3\u2010c]pyridine derivatives as guest dopants through supramolecular self\u2010assembly. By tuning the solvent evaporation rate, the materials can be prepared as either ordered, tightly packed crystals or disordered amorphous (glassy) materials. Enabled by the combined effects of the flexible alkyl chains and abundant hydrogen\u2010bonding sites in the BTA host, these doped materials overcome the conventional morphology constraints and exhibit excellent dual\u2010morphology (crystalline\/glassy) RTP. The phosphorescence quantum yield reaches &gt; 60%, and the afterglow remains stable even up to 460 K. To the best of our knowledge, this is the first doped RTP system that exhibits dual\u2010morphology emission.<\/jats:p>","DOI":"10.1002\/anie.4158258","type":"journal-article","created":{"date-parts":[[2026,3,19]],"date-time":"2026-03-19T09:44:58Z","timestamp":1773913498000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Organic Materials With Dual\u2010Morphology (Crystalline\/Glassy) and High\u2010Temperature Phosphorescence Emission"],"prefix":"10.1002","volume":"65","author":[{"given":"Lei","family":"Wang","sequence":"first","affiliation":[{"name":"School of Chemistry and Materials Engineering Wenzhou University  Wenzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chuanli","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Materials Engineering Wenzhou University  Wenzhou P. R. 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Numbers 726433 (for BTA) 233347 (PTA) and 154423 (BDA) Contain the Supplementary Crystallographic Data for This Paper. 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