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Herein, we report a platinum catalyst supported on the porous hydroxyl lanthanum oxide, which is prepared via glycine combustion method followed by a reduction process. The optimized 0.8%Pt\/La catalyst, which is featured by Pt single\u2010atom dispersed on a La\n 2<\/jats:sub>\n (OH)\n 2<\/jats:sub>\n \n x<\/jats:sub>\n <\/jats:italic>\n O\n 3\u20102<\/jats:sub>\n \n x<\/jats:sub>\n <\/jats:italic>\n support, exhibits an extraordinary catalytic performance towards APRM. A H\n 2<\/jats:sub>\n production rate of 7672 \u00b5mol\n H2<\/jats:sub>\n g\n cat<\/jats:sub>\n \u22121<\/jats:sup>\n min\n \u22121<\/jats:sup>\n and an average turnover frequency (ATOF) of 11973 h\n \u20121<\/jats:sup>\n are obtained, which is preponderant to the state\u2010of\u2010the\u2010art catalysts. An in\u2010depth investigation based on kinetic isotope analysis, in situ spectroscopy characterizations and theoretical calculations substantiates that Pt single atom coordinated with adjacent lattice hydroxyl (OH\n L<\/jats:sub>\n ) with electron transfer from Pt to support serves as the intrinsic active site, in which the Pt\n \n \u03b4<\/jats:sup>\n <\/jats:italic>\n +<\/jats:sup>\n site promotes the dehydrogenation of methoxyl whilst lattice hydroxyl directly participates in the oxidative coupling process (CH\n 2<\/jats:sub>\n O* + OH\n L<\/jats:sub>\n \u2192 CH\n 2<\/jats:sub>\n OOH*). Furthermore, the Pt\n \n \u03b4<\/jats:sup>\n <\/jats:italic>\n +<\/jats:sup>\n \u2212(OH\n L<\/jats:sub>\n )\n \n x<\/jats:sub>\n <\/jats:italic>\n \u2212La interface sites can remarkably reduce the energy barrier of CH\n 2<\/jats:sub>\n OOH* dehydrogenation (rate\u2010determining step), and the resulting hydroxyl vacancies can boost H\n 2<\/jats:sub>\n O dissociation to recover consumed OH\n L<\/jats:sub>\n , accounting for the exceptional catalytic performance.\n <\/jats:p>","DOI":"10.1002\/anie.4185228","type":"journal-article","created":{"date-parts":[[2026,4,7]],"date-time":"2026-04-07T08:56:51Z","timestamp":1775552211000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Lattice Hydroxyl\u2010Assisted Platinum Single Atom Catalyst Toward Hydrogen Production From Methanol Aqueous Reforming"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-6494-0825","authenticated-orcid":false,"given":"Hao","family":"Meng","sequence":"first","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing University of Chemical Technology Beijing P. 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