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However, the development of high\u2010performance separation membranes faces fundamental material challenges, as amorphous polymeric materials typically exhibit poorly controlled pore size distributions while crystalline porous materials encounter intrinsic difficulties in forming continuous, defect\u2010free membranes at the macroscopic scale owing to inevitable crystal boundaries. Despite their exceptional structural tunability and separation potential, MOF membranes face fundamental challenges in defect\u2010free fabrication due to intrinsic crystallinity constraints. Integrating the structural precision of crystalline MOFs with the adaptivity of polymers, we successfully fabricated a macroscopic, free\u2010standing, and flexible monolithic pure MOF membrane through interface\u2010induced coordination of Co\n                    <jats:sup>2+<\/jats:sup>\n                    with the flexible multidentate amino acid ligand 2,6\u2010diaminopimelic acid (DAP). The flexible alkyl\u2010chain backbone suppresses long\u2010range crystallization and reduces interfacial strain during continuous membrane growth. Locally defined Co\u2013amino\u2010acid coordination units preserve a framework scaffold, while conformationally flexible alkyl segments impart guest\u2010responsive latent free volume. The flexible Co\u2010DAP membrane exhibits guest\u2010responsive dynamic porosity, in which hydration generates water\u2010accessible transport pathways that regulate hydrated\u2010state molecular and ionic transport, enabling osmotically driven water\/ion separation through coupled transport and interfacial electrostatic effects under conditions relevant to forward osmosis.\n                  <\/jats:p>","DOI":"10.1002\/anie.4290539","type":"journal-article","created":{"date-parts":[[2026,10,4]],"date-time":"2026-10-04T10:24:33Z","timestamp":1791109473000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Interface\u2010Induced Growth of Macroscopic, Free\u2010Standing, and Flexible Monolithic Pure MOF Membrane With Adaptive Porosity"],"prefix":"10.1002","author":[{"given":"Yuan","family":"Zhao","sequence":"first","affiliation":[{"name":"Hefei National Laboratory for Physical Sciences at the Microscale, School of 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