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Despite advances in advanced oxidation processes, there remains a lack of generalizable methods that reliably modulate\n                    <jats:sup>1<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    selectivity. Here, we propose a descriptor\u2010assisted coordination modulation strategy, in which machine\u2010learning analysis identifies the d\u2010band center as an important electronic descriptor associated with\n                    <jats:sup>1<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    selectivity. Through N\u2010coordination modulation, the CoN\n                    <jats:sub>5<\/jats:sub>\n                    catalyst exhibited near\u2010complete\n                    <jats:sup>1<\/jats:sup>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    selectivity among the quantified reactive oxygen species (ROS) with a steady\u2010state concentration of 394 \u00b5M, outperforming recent reports. As an internal\u2010circulation pre\u2010oxidation module, the CoN\n                    <jats:sub>5<\/jats:sub>\n                    \/peroxymonosulfate (CoN\n                    <jats:sub>5<\/jats:sub>\n                    \/PMS) system continuously raised wastewater biochemical oxygen demand\/chemical oxygen demand (BOD\/COD) to above 0.5 over 192\u00a0h, increased bioavailable dissolved organic matter (DOM), and showed high microbiome compatibility, evidenced by reduced\n                    <jats:italic>Vibrio fischeri<\/jats:italic>\n                    inhibition and microbial diversity ordination clustering near the background with greater shared\u2010taxa overlap. This system also enabled selective thioanisole oxidation, achieving 90.6% conversion and 99.5% selectivity, with green synthesis potential demonstrated in a three\u2010chamber continuous single\u2010pass reactor. These results establish a generalizable coordination principle for steering ROS pathways and provide a deployable, low\u2010ecological\u2010risk route for both mixed wastewater treatment and green chemical synthesis.\n                  <\/jats:p>","DOI":"10.1002\/anie.4329489","type":"journal-article","created":{"date-parts":[[2026,8,8]],"date-time":"2026-08-08T10:53:15Z","timestamp":1786186395000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Universal Fenton\u2010Like Strategy for Selective Generation of\n                    <sup>1<\/sup>\n                    O\n                    <sub>2<\/sub>\n                    in Mixed Industrial Wastewater Treatment and Green Chemical Synthesis"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-4207-0867","authenticated-orcid":false,"given":"Zhiyong","family":"Zhao","sequence":"first","affiliation":[{"name":"MOE Key Laboratory of Pollution Processes and Environmental Criteria Tianjin Key Laboratory of Environmental Remediation and Pollution Control College of Environmental Science and Engineering Nankai University  Tianjin P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7257-8539","authenticated-orcid":false,"given":"Shuai","family":"Yue","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Pollution Processes and Environmental Criteria Tianjin Key Laboratory of Environmental Remediation and Pollution Control College of Environmental Science and Engineering Nankai University  Tianjin P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mengxue","family":"Yang","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Pollution Processes and Environmental Criteria Tianjin Key Laboratory of Environmental Remediation and Pollution Control College of Environmental Science and Engineering Nankai University  Tianjin P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiachen","family":"Zhang","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Pollution Processes and Environmental Criteria Tianjin Key Laboratory of Environmental Remediation and Pollution Control College of Environmental Science and Engineering Nankai University  Tianjin P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fei","family":"Li","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Pollution Processes and Environmental Criteria Tianjin Key Laboratory of Environmental Remediation and Pollution Control College of Environmental Science and Engineering Nankai University  Tianjin P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanxiao","family":"Li","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Pollution Processes and Environmental Criteria Tianjin Key Laboratory of Environmental Remediation and Pollution Control College of Environmental Science and Engineering Nankai University  Tianjin P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6182-9213","authenticated-orcid":false,"given":"Pengfei","family":"Wang","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Pollution Processes and Environmental Criteria Tianjin Key Laboratory of Environmental Remediation and Pollution Control College of Environmental Science and Engineering Nankai University  Tianjin P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1575-5946","authenticated-orcid":false,"given":"Sihui","family":"Zhan","sequence":"additional","affiliation":[{"name":"MOE Key Laboratory of Pollution Processes and Environmental Criteria Tianjin Key Laboratory of Environmental Remediation and Pollution Control College of Environmental Science and Engineering Nankai University  Tianjin P.R. China"},{"name":"School of Environmental Science and Engineering Tianjin University  Tianjin P.R. 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