{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,10]],"date-time":"2026-10-10T16:48:44Z","timestamp":1791650924953,"version":"4.3.4"},"reference-count":69,"publisher":"Wiley","issue":"42","license":[{"start":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T00:00:00Z","timestamp":1787356800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T00:00:00Z","timestamp":1787356800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,10,12]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Attracted by \u223c100% element recovery rate, direct regeneration of spent NCM (SNCM) has been deemed as next\u2010generation recycling strategy. However, practical SNCM is always mixed with inactive impurities (PVDF and conductive carbon), which introduces undesirable heteroatoms and serious secondary damage, resulting in inferior performance. Herein, we propose a vacuum\u2010assisted impurities removing strategy to upcycle SNCM with tailored spin states of vital elements. Accompanied with triggered electronic configuration reconstruction of Ni\/Mn species, the as\u2010formed strengthened Ni\n                    <jats:sup>2+<\/jats:sup>\n                    \u2013O\n                    <jats:sup>2\u2212<\/jats:sup>\n                    \u2013Mn\n                    <jats:sup>4+<\/jats:sup>\n                    superexchange brings about built\u2010in electric field and robust lattice structures with minor distortions. Meanwhile, oxygen vacancy formation energy increases about 1.1\u00a0eV, and electron localization effect is greatly alleviated, leading to durable stability and rapid reaction kinetics. The as\u2010optimized samples exhibit high capacity retention of 93.5% at 1.0 C after cycling. Even at ultra\u2010high rates of 8.0 C and 10.0 C, they could retain 116.7 and 110.4\u00a0mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Assisted by kinetics analysis and in\/ex situ measurements, enhanced Li\u2010diffusion and eliminated internal strains are revealed. Moreover, this strategy could be applied to upcycle spent NCM613, Ni65 and NCM811. This work is expected to illustrate the advantages of electronic configuration reconstruction and superexchange interaction creation during regeneration, meanwhile offer full\u2010process regeneration strategies toward upcycled NCM.\n                  <\/jats:p>","DOI":"10.1002\/anie.4391410","type":"journal-article","created":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T09:07:38Z","timestamp":1787389658000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Vacuum\u2010Assisted Impurities Removing Triggered Electronic Configuration Reconstruction of Spent NCM for Ultrafast Lithium Storage"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-2661-4812","authenticated-orcid":false,"given":"Chao","family":"Zhu","sequence":"first","affiliation":[{"name":"School of Minerals Processing and Bioengineering Central South University  Changsha P. R. 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