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However, rationally synthesizing target MOFs with NH\n                    <jats:sub>3<\/jats:sub>\n                    tolerance and reversible uptake still remains challenging. Here, we present a hydrogen\u2010bonded metal\u2010complex framework (ALP\u2010HOF\u20101) that can isostructurally transform to a porous MOF (ALP\u2010MOF\u20104) via a ligand substitution strategy to dramatically enhance NH\n                    <jats:sub>3<\/jats:sub>\n                    tolerance and reversibility. The remarkable NH\n                    <jats:sub>3<\/jats:sub>\n                    tolerance was unambiguously confirmed by the retention of NH\n                    <jats:sub>3<\/jats:sub>\n                    adsorption capacities after consecutive adsorption\/desorption cycles and breakthrough experiments. At 298\u00a0K and 1.0\u00a0bar, ALP\u2010MOF\u20104 exhibits a high NH\n                    <jats:sub>3<\/jats:sub>\n                    packing density comparable to liquid NH\n                    <jats:sub>3<\/jats:sub>\n                    . X\u2212ray photoelectron spectroscopy and computational studies ascertain the binding domains of adsorbed NH\n                    <jats:sub>3<\/jats:sub>\n                    molecules. Open metal sites, Br\u00f8nsted basic carbonyl (\u2500C\u2550O), and acidic \u2500NH groups in ALP\u2010MOF\u20104 act cooperatively as preferred anchoring sites for NH\n                    <jats:sub>3<\/jats:sub>\n                    capture, resulting in excellent trace NH\n                    <jats:sub>3<\/jats:sub>\n                    capture performance under mixed NH\n                    <jats:sub>3<\/jats:sub>\n                    , CO\n                    <jats:sub>2<\/jats:sub>\n                    , and N\n                    <jats:sub>2<\/jats:sub>\n                    streams with effluent NH\n                    <jats:sub>3<\/jats:sub>\n                    below 50\u00a0ppm. The structural integrity and recyclability of ALP\u2010MOF\u20104 demonstrate its potential as a durable NH\n                    <jats:sub>3<\/jats:sub>\n                    sorbent. This work provides design principles for rational transformations from HOFs to MOFs featuring active\u2010site environments for selective gas capture.\n                  <\/jats:p>","DOI":"10.1002\/anie.4524818","type":"journal-article","created":{"date-parts":[[2026,4,7]],"date-time":"2026-04-07T09:49:13Z","timestamp":1775555353000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Isostructural Transformation From a Hydrogen\u2010Bonded Metal\u2010Complex Framework to a Metal\u2013Organic Framework for Enhanced Ammonia Tolerance"],"prefix":"10.1002","volume":"65","author":[{"given":"Xiao\u2010Li","family":"Yu","sequence":"first","affiliation":[{"name":"Key Laboratory of Eco\u2010Chemical Engineering, Ministry of Education, International Science and Technology Cooperation Base of Eco\u2010Chemical Engineering and Green Manufacturing College of Chemistry and Molecular Engineering Qingdao University of Science and Technology  Qingdao P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zongwei","family":"Jia","sequence":"additional","affiliation":[{"name":"Key Laboratory of Eco\u2010Chemical Engineering, Ministry of Education, International Science and Technology Cooperation Base of Eco\u2010Chemical Engineering and Green Manufacturing College of Chemistry and Molecular Engineering Qingdao University of Science and Technology  Qingdao P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9690-9259","authenticated-orcid":false,"given":"Hongliang","family":"Huang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Advanced Separation Membrane Materials, School of Chemical Engineering and Technology Tiangong University  Tianjin P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7275-4846","authenticated-orcid":false,"given":"Lei","family":"Wang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Eco\u2010Chemical Engineering, Ministry of Education, International Science and Technology Cooperation Base of Eco\u2010Chemical Engineering and Green Manufacturing College of Chemistry and Molecular Engineering Qingdao University of Science and Technology  Qingdao P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0395-1111","authenticated-orcid":false,"given":"Yi","family":"Han","sequence":"additional","affiliation":[{"name":"Key Laboratory of Eco\u2010Chemical Engineering, Ministry of Education, International Science and Technology Cooperation Base of Eco\u2010Chemical Engineering and Green Manufacturing College of Chemistry and Molecular Engineering Qingdao University of Science and Technology  Qingdao P. R. 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