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Herein, we propose a mild ethylene\u2010glycol\u2013assisted treatment that in situ constructs a coherent surface\u2010to\u2010bulk architecture within NaNi\n                    <jats:sub>1\/3<\/jats:sub>\n                    Fe\n                    <jats:sub>1\/3<\/jats:sub>\n                    Mn\n                    <jats:sub>1\/3<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    (NFM) particles, comprising a nanoscale surface rock\u2010salt layer, a depth\u2010dependent Na\u2010vacancy gradient, and a Na\u2010deficient bulk. This hierarchical configuration locks the surface chemistry while opening continuous Na\n                    <jats:sup>+<\/jats:sup>\n                    percolation pathways across the surface\u2013bulk junction, thereby flattening radial (de)sodiation heterogeneity and steering a more uniform, highly reversible phase evolution during prolonged cycling. As a result, the modified sample exhibits outstanding fast\u2010charging performance, delivering 107.6 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 5C (600\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) with 81.6% capacity retention after 400 cycles. This work highlights gradient interphase coupled with Na\u2010vacancy engineering as an effective strategy to develop high\u2010performance layered oxide cathodes for sodium\u2010ion batteries.\n                  <\/jats:p>","DOI":"10.1002\/anie.4606157","type":"journal-article","created":{"date-parts":[[2026,8,11]],"date-time":"2026-08-11T12:21:21Z","timestamp":1786450881000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Hierarchical Surface\u2010to\u2010Bulk Architecture for High\u2010Performance O3\u2010Type Sodium Cathodes"],"prefix":"10.1002","volume":"65","author":[{"given":"Zhiqi","family":"Yang","sequence":"first","affiliation":[{"name":"School of Materials Science and Engineering Tongji University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yi","family":"Li","sequence":"additional","affiliation":[{"name":"School of Materials Science and Engineering Tongji University  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yali","family":"Liang","sequence":"additional","affiliation":[{"name":"Clean Nano Energy Center State Key Laboratory of MetastableMaterials Science and Technology Yanshan University  Qinhuangdao P.R. 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