{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T15:44:45Z","timestamp":1792079085597,"version":"4.4.0"},"reference-count":44,"publisher":"Wiley","issue":"36","license":[{"start":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T00:00:00Z","timestamp":1782950400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T00:00:00Z","timestamp":1782950400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2021YFA1500500"],"award-info":[{"award-number":["2021YFA1500500"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2022YFA1505700"],"award-info":[{"award-number":["2022YFA1505700"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22525021"],"award-info":[{"award-number":["22525021"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22221003"],"award-info":[{"award-number":["22221003"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22250007"],"award-info":[{"award-number":["22250007"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22361162655"],"award-info":[{"award-number":["22361162655"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22308346"],"award-info":[{"award-number":["22308346"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22522907"],"award-info":[{"award-number":["22522907"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22475044"],"award-info":[{"award-number":["22475044"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22204158"],"award-info":[{"award-number":["22204158"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100011202","name":"State Key Laboratory of Catalysis","doi-asserted-by":"publisher","award":["2024SKL\u2010A\u2010011"],"award-info":[{"award-number":["2024SKL\u2010A\u2010011"]}],"id":[{"id":"10.13039\/501100011202","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100017128","name":"Science Fund for Distinguished Young Scholars of Anhui Province","doi-asserted-by":"publisher","award":["2408085J008"],"award-info":[{"award-number":["2408085J008"]}],"id":[{"id":"10.13039\/100017128","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,9,1]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The development of robust catalysts for CO\n                    <jats:sub>2<\/jats:sub>\n                    methanation under intermittent operating conditions is key to harnessing renewable energy sources such as wind and solar. However, this pursuit faces two major obstacles. The heating\u2010cooling cycles induce prolonged thermal stress, resulting in catalyst deactivation. Moreover, the temperature\u2010sensitive selectivity hampers the ability to maintain high methane yield, leading to undesired by\u2010products. Herein, we report cobalt nanoparticles confined within carbon matrices, which achieved 82.3% CO\n                    <jats:sub>2<\/jats:sub>\n                    conversion and &gt; 99% CH\n                    <jats:sub>4<\/jats:sub>\n                    selectivity over multiple heating\u2010cooling cycles toward intermittent CO\n                    <jats:sub>2<\/jats:sub>\n                    methanation. The catalyst robustness arises from the low coefficient of thermal expansion and high thermal conductivity of the carbon matrix, which effectively mitigates thermal stress during temperature fluctuations. Mechanistic studies confirm that the reaction proceeds via a formate pathway, which contributes to the high CH\n                    <jats:sub>4<\/jats:sub>\n                    selectivity across a wide temperature range. These insights provide a design framework for developing robust catalysts, advancing CO\n                    <jats:sub>2<\/jats:sub>\n                    methanation performance, and the efficient use of fluctuating renewable energy sources.\n                  <\/jats:p>","DOI":"10.1002\/anie.4611954","type":"journal-article","created":{"date-parts":[[2026,7,2]],"date-time":"2026-07-02T17:07:58Z","timestamp":1783012078000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Cobalt Nanoparticles Confined in Defective Carbon Matrices for Robust Intermittent CO\n                    <sub>2<\/sub>\n                    Methanation"],"prefix":"10.1002","volume":"65","author":[{"given":"Jingzhong","family":"Qin","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering Southeast University  Nanjing Jiangsu China"},{"name":"Deep Space Exploration Laboratory  Hefei China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shuaishuai","family":"Yin","sequence":"additional","affiliation":[{"name":"Department of Chemical Physics Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Strongly\u2010Coupled Quantum Matter Physics of Chinese Academy of Sciences University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Caizhi","family":"Yu","sequence":"additional","affiliation":[{"name":"School of Chemistry &amp; Chemical Engineering Anhui University of Technology  Ma'anshan Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuhang","family":"Tao","sequence":"additional","affiliation":[{"name":"School of Chemistry &amp; Chemical Engineering Anhui University of Technology  Ma'anshan Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiayu","family":"Mu","sequence":"additional","affiliation":[{"name":"School of Chemistry &amp; Chemical Engineering Anhui University of Technology  Ma'anshan Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Menglin","family":"Wang","sequence":"additional","affiliation":[{"name":"Department of Chemical Physics Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Strongly\u2010Coupled Quantum Matter Physics of Chinese Academy of Sciences University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiahua","family":"Luo","sequence":"additional","affiliation":[{"name":"Department of Chemical Physics Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Strongly\u2010Coupled Quantum Matter Physics of Chinese Academy of Sciences University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lei","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Chemical Physics Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Strongly\u2010Coupled Quantum Matter Physics of Chinese Academy of Sciences University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yuhan","family":"Zhou","sequence":"additional","affiliation":[{"name":"Department of Chemical Physics Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Strongly\u2010Coupled Quantum Matter Physics of Chinese Academy of Sciences University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ziyi","family":"Yan","sequence":"additional","affiliation":[{"name":"Department of Chemical Physics Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Strongly\u2010Coupled Quantum Matter Physics of Chinese Academy of Sciences University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lijun","family":"Zhang","sequence":"additional","affiliation":[{"name":"School of Chemistry &amp; Chemical Engineering Anhui University of Technology  Ma'anshan Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4913-7492","authenticated-orcid":false,"given":"Yunqian","family":"Dai","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Southeast University  Nanjing Jiangsu China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3925-772X","authenticated-orcid":false,"given":"Wenlong","family":"Wu","sequence":"additional","affiliation":[{"name":"School of Chemistry &amp; Chemical Engineering Anhui University of Technology  Ma'anshan Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0348-7910","authenticated-orcid":false,"given":"Hongliang","family":"Li","sequence":"additional","affiliation":[{"name":"Deep Space Exploration Laboratory  Hefei China"},{"name":"Department of Chemical Physics Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Strongly\u2010Coupled Quantum Matter Physics of Chinese Academy of Sciences University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8812-0298","authenticated-orcid":false,"given":"Jie","family":"Zeng","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Southeast University  Nanjing Jiangsu China"},{"name":"Deep Space Exploration Laboratory  Hefei China"},{"name":"Department of Chemical Physics Hefei National Research Center for Physical Sciences at the Microscale University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Strongly\u2010Coupled Quantum Matter Physics of Chinese Academy of Sciences University of Science and Technology of China  Hefei Anhui People's Republic of China"},{"name":"Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes University of Science and Technology of China  Hefei Anhui People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,2]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41563\u2010023\u201001540\u20101"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1039\/C9EE02410G"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010019\u20101681\u20106"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202317669"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201047403\u20104"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44286\u2010024\u201000122\u20105"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202425888"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057954\u20109"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201046216\u20109"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.1c00756"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2021.214204"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057611\u20101"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/0009\u20102509(91)80144\u2010N"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929-022-00842-y"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1039\/C7CC04926A"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010017\u201001734\u20107"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b10864"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.aan6245"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201046513\u20103"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201046388\u20104"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/S1872\u20105805(22)60603\u20106"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcomc.2024.100434"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0078037"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2017.08.048"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1007\/s12274\u2010023\u20106199\u20104"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1590\/1980\u20105373\u2010mr\u20102017\u20100787"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c02847"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.abl9478"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2022.122277"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201802167"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacsau.2c00605"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2004.03.005"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.add1267"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201025118\u20100"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.carbon.2008.02.012"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.8b02889"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2CY00914E"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010023\u201001040\u20100"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010022\u201000870\u20108"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202401386"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c13711"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2024.124549"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.4c01230"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.3c00189"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.4611954","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.4611954","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.4611954","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T14:54:27Z","timestamp":1792076067000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.4611954"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,2]]},"references-count":44,"journal-issue":{"issue":"36","published-print":{"date-parts":[[2026,9,1]]}},"alternative-id":["10.1002\/anie.4611954"],"URL":"https:\/\/doi.org\/10.1002\/anie.4611954","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,2]]},"assertion":[{"value":"2026-04-18","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-15","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-02","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e4611954"}}