{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T02:47:00Z","timestamp":1790045220289,"version":"4.0.1"},"reference-count":61,"publisher":"Wiley","issue":"15","license":[{"start":{"date-parts":[[2026,2,25]],"date-time":"2026-02-25T00:00:00Z","timestamp":1771977600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,2,25]],"date-time":"2026-02-25T00:00:00Z","timestamp":1771977600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22305038"],"award-info":[{"award-number":["22305038"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22471271"],"award-info":[{"award-number":["22471271"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22222510"],"award-info":[{"award-number":["22222510"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["52302008"],"award-info":[{"award-number":["52302008"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003392","name":"Natural Science Foundation of Fujian Province","doi-asserted-by":"publisher","award":["2023J02026"],"award-info":[{"award-number":["2023J02026"]}],"id":[{"id":"10.13039\/501100003392","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100003392","name":"Natural Science Foundation of Fujian Province","doi-asserted-by":"publisher","award":["2024J08102"],"award-info":[{"award-number":["2024J08102"]}],"id":[{"id":"10.13039\/501100003392","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004739","name":"Youth Innovation Promotion Association of the Chinese Academy of Sciences","doi-asserted-by":"publisher","award":["Y2023082"],"award-info":[{"award-number":["Y2023082"]}],"id":[{"id":"10.13039\/501100004739","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,4,6]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The development of deep ultraviolet nonlinear optical (DUV NLO) materials with simultaneous high performance across multiple properties remains a significant challenge. Key properties, such as a short UV cutoff edge, strong second\u2010harmonic generation (SHG) response, and suitable birefringence, are often mutually constrained. This study introduces a novel \u201cThree Birds with One Stone\u201d strategy, utilizing a confined \u03c0\u2010conjugated functional group, [OOCCH(NH\n                    <jats:sub>3<\/jats:sub>\n                    )CH\n                    <jats:sub>2<\/jats:sub>\n                    SO\n                    <jats:sub>3<\/jats:sub>\n                    ]\n                    <jats:sup>\u2212<\/jats:sup>\n                    , integrated into the sulfate framework. The approach enhances both polarizability anisotropy and hyperpolarizability while preserving the large band gap inherent to sulfates. This strategy achieves a breakthrough in balancing key performance metrics. Using this new design, we successfully synthesized a novel DUV NLO sulfonate, Li[OOCCH(NH\n                    <jats:sub>3<\/jats:sub>\n                    )CH\n                    <jats:sub>2<\/jats:sub>\n                    SO\n                    <jats:sub>3<\/jats:sub>\n                    ] (LCNS), which demonstrates excellent optical properties, including a short UV cutoff edge (177\u00a0nm), a record SHG response (4.5 \u00d7 KDP), and exceptional birefringence (0.090@589\u00a0nm) among DUV NLO sulfonates. This work not only provides a promising candidate for DUV NLO applications but also introduces an innovative strategy for the development of advanced DUV NLO materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.4703576","type":"journal-article","created":{"date-parts":[[2026,3,8]],"date-time":"2026-03-08T08:18:06Z","timestamp":1772957886000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Confinement \u03c0\u2010Conjugated Moiety Tailoring to Achieve Record Deep\u2010UV Nonlinearity in Sulfates"],"prefix":"10.1002","volume":"65","author":[{"given":"Yujie","family":"Fan","sequence":"first","affiliation":[{"name":"State Key Laboratory of Functional Crystals and Devices Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian China"},{"name":"University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chengming","family":"Hu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Functional Crystals and Devices Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lingli","family":"Wu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Functional Crystals and Devices Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian China"},{"name":"University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1895-4980","authenticated-orcid":false,"given":"Chensheng","family":"Lin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Functional Crystals and Devices Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chao","family":"Wang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Functional Crystals and Devices Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian China"},{"name":"University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4246-0964","authenticated-orcid":false,"given":"Huixin","family":"Fan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Functional Crystals and Devices Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tao","family":"Yan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Functional Crystals and Devices Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9062-8931","authenticated-orcid":false,"given":"Min","family":"Luo","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Functional Crystals and Devices Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian China"},{"name":"University of Chinese Academy of Sciences  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,2,25]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1007\/s00340\u2010009\u20103554\u20104"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/457953a"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.3c00755"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202425384"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.accounts.8b00649"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c11645"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.0c00796"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c07256"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201803482"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3CS00691C"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c08403"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202115871"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202201616"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202315133"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwac017"},{"key":"e_1_2_7_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202310407"},{"key":"e_1_2_7_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202115855"},{"key":"e_1_2_7_19_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.scriptamat.2022.114764"},{"key":"e_1_2_7_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202315434"},{"key":"e_1_2_7_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202102107"},{"key":"e_1_2_7_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b00138"},{"key":"e_1_2_7_23_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6b06053"},{"key":"e_1_2_7_24_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b10209"},{"key":"e_1_2_7_25_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja411272y"},{"key":"e_1_2_7_26_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.6b03333"},{"key":"e_1_2_7_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja504319x"},{"key":"e_1_2_7_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja504319x"},{"key":"e_1_2_7_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.7b12518"},{"key":"e_1_2_7_30_1","doi-asserted-by":"publisher","DOI":"10.1016\/S0925\u20103467(00)00027\u20106"},{"key":"e_1_2_7_31_1","doi-asserted-by":"publisher","DOI":"10.1039\/c4tc00079j"},{"key":"e_1_2_7_32_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201209151"},{"key":"e_1_2_7_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.8b00545"},{"key":"e_1_2_7_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202001855"},{"key":"e_1_2_7_35_1","doi-asserted-by":"publisher","DOI":"10.1103\/PhysRevLett.7.118"},{"key":"e_1_2_7_36_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jcrysgro.2018.02.028"},{"key":"e_1_2_7_37_1","doi-asserted-by":"publisher","DOI":"10.1039\/C5CP06884C"},{"key":"e_1_2_7_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c02764"},{"key":"e_1_2_7_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202200228"},{"key":"e_1_2_7_40_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.90396"},{"key":"e_1_2_7_41_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.2c00225"},{"key":"e_1_2_7_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adom.202401332"},{"key":"e_1_2_7_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202112844"},{"key":"e_1_2_7_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemmater.8b03310"},{"key":"e_1_2_7_45_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202006671"},{"key":"e_1_2_7_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202016372"},{"key":"e_1_2_7_47_1","doi-asserted-by":"publisher","DOI":"10.31635\/ccschem.023.202202582"},{"key":"e_1_2_7_48_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5QI01311A"},{"key":"e_1_2_7_49_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202315311"},{"key":"e_1_2_7_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202110740"},{"key":"e_1_2_7_51_1","doi-asserted-by":"publisher","DOI":"10.1039\/D2SC01910H"},{"key":"e_1_2_7_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202304858"},{"key":"e_1_2_7_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/lpor.202500105"},{"key":"e_1_2_7_54_1","unstructured":"Deposition numbers 2501734 for Li[OOCCH(NH3)CH2SO3] contain the supplementary crystallographic data for this paper. These data are provided free of charge by the joint Cambridge Crystallographic Data Centre and Fachinformationszentrum Karlsruhe Access Structures service."},{"key":"e_1_2_7_55_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.9b03858"},{"key":"e_1_2_7_56_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202408551"},{"key":"e_1_2_7_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.201911187"},{"key":"e_1_2_7_58_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202406318"},{"key":"e_1_2_7_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/lpor.202502128"},{"key":"e_1_2_7_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/small.202502744"},{"key":"e_1_2_7_61_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3QI02465B"},{"key":"e_1_2_7_62_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.1656857"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.4703576","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.4703576","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.4703576","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,4,7]],"date-time":"2026-04-07T04:39:53Z","timestamp":1775536793000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.4703576"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,2,25]]},"references-count":61,"journal-issue":{"issue":"15","published-print":{"date-parts":[[2026,4,6]]}},"alternative-id":["10.1002\/anie.4703576"],"URL":"https:\/\/doi.org\/10.1002\/anie.4703576","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,2,25]]},"assertion":[{"value":"2025-12-16","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-17","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-02-25","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e4703576"}}