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However, their integration has been hampered by inadequate dispersibility in low\u2010polarity solvents. Herein, the two\u2010dimensional MOF materials, Cu\u2010TCPP and Zn\u2010TCPP, were synthesized and precisely infiltrated into the upper region of the active layer through an anti\u2010solvent strategy, which significantly enhanced charge transport through continuous\n                    <jats:italic>\u03c0<\/jats:italic>\n                    \u2010d conjugation within the MOF layers. Moreover, intermolecular interactions between MOFs and acceptor L8\u2010BO, including metal\u2010center coordination and\n                    <jats:italic>\u03c0<\/jats:italic>\n                    \u2010\n                    <jats:italic>\u03c0<\/jats:italic>\n                    effect enabled by conjugated porphyrin ligands, facilitate superior molecular packing, a double\u2010fibril structure, and favorable vertical phase separation. Consequently, Zn\u2010TCPP\u2010incorporated D18:L8\u2010BO OSCs achieve an outstanding efficiency of 20.70%, ranking among the highest reported values for binary devices. Meanwhile, the anchoring effect of MOFs significantly enhances the morphological stability of the active layer, endowing the OSCs with over twofold improvement in operational stability. This work not only opens a novel pathway for integrating high\u2010performance MOF materials into OSCs but also establishes a promising paradigm for constructing efficient charge transport channels and fabricating highly stable, high\u2010performance organic photovoltaics.\n                  <\/jats:p>","DOI":"10.1002\/anie.4785538","type":"journal-article","created":{"date-parts":[[2026,5,30]],"date-time":"2026-05-30T11:45:36Z","timestamp":1780141536000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Two\u2010Dimensional Metal\u2010Organic Frameworks as Charge Extraction Media Enabling Binary Organic Solar Cells With 20.70% Efficiency"],"prefix":"10.1002","volume":"65","author":[{"given":"Ziwei","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Bioinspired Interfacial Materials Science International Research Center For Carbon Neutralization Hangzhou International Innovation 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