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However, DAFCs face significant challenges in using high\u2010loading Pt\u2010based catalysts at both the anode and cathode, where the alcohol oxidation reaction and oxygen reduction reaction still suffer slow kinetics, as well as alcohol crossover causing cathode poisoning. Here, we report a breakthrough in alternative solar\u2010driven redox\u2010catalyzed direct alcohol fuel cells (SR\u2010DAFCs), that avoid using Pt catalysts and can operate with a range of alcohols. They mechanistically alter the conventional solid\/liquid\/gas heterogeneous electrocatalytic reaction pathways, into liquid homogeneous organic redox couples that mediated alcohol photocatalytic oxidation reaction at the anode, and oxygen electrochemical reduction reaction at cathode. The SR\u2010DAFCs exhibited record high\u2010power density up to 319.2\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    with various alcohols feed, that is 3 times higher than traditional DAFC, demonstrating great potential of using unrefined alcohols as an economical fuel source for wider applications.\n                  <\/jats:p>","DOI":"10.1002\/anie.4885694","type":"journal-article","created":{"date-parts":[[2026,8,20]],"date-time":"2026-08-20T12:17:47Z","timestamp":1787228267000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Solar\u2010Driven Redox\u2010Catalyzed Direct Alcohol Fuel Cells"],"prefix":"10.1002","volume":"65","author":[{"given":"Le","family":"Yang","sequence":"first","affiliation":[{"name":"College of Chemistry and Chemical Engineering Southwest University  Chongqing China"},{"name":"State Key Laboratory for Physical Chemistry of Solid Surfaces  Xiamen Fujian 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