{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T18:40:15Z","timestamp":1792262415234,"version":"4.4.0"},"reference-count":79,"publisher":"Wiley","issue":"43","license":[{"start":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T00:00:00Z","timestamp":1787961600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T00:00:00Z","timestamp":1787961600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22438009"],"award-info":[{"award-number":["22438009"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22278285"],"award-info":[{"award-number":["22278285"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22608370"],"award-info":[{"award-number":["22608370"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["U24A20535"],"award-info":[{"award-number":["U24A20535"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,10,19]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The formidable exciton effect inherent in organic semiconductors fundamentally restricts free charge carrier generation, thereby impeding photocatalytic redox efficiency. Facilitating spontaneous exciton dissociation and lowering exciton binding energy are essential for maximizing charge utilization. Herein, we report a conformation\u2010locking strategy to engineer a thiazole\u2010rich mixed\u2010linkage donor\u2013acceptor conjugated covalent organic framework (SBt\u2010Tapt) via post\u2010synthetic cyclization. The seamless integration of sulfur heteroatoms into a rigid, thiazole\u2010bridged framework significantly enhances \u03c0\u2010conjugated and electronic polarizability. Crucially, this structural reinforcement lowers the exciton activation energy below to 25 meV, triggering spontaneous exciton dissociation, extending carrier lifetimes, and yielding a proliferation of free charge carriers at room temperature. Mechanistic insights elucidate that the thiazole moieties synergistically activate adjacent phenyl units for O\n                    <jats:sub>2<\/jats:sub>\n                    reduction while simultaneously lowering the energy barrier for H\n                    <jats:sub>2<\/jats:sub>\n                    O oxidation at benzothiophene sites. This dual\u2010pathway mechanism drives efficient H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    photosynthesis with robust operational stability exceeding 100\u00a0h. Notably, utilizing phenolic pollutants as proton donors, SBt\u2010Tapt delivers an exceptional H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    evolution rate of 8.99\u00a0mmol g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    alongside effective pollutant mineralization. This study elucidates a profound structure\u2013activity relationship (SAR) and establishes conformation locking as a potent excitonic engineering paradigm for developing high performance organic photocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.4914496","type":"journal-article","created":{"date-parts":[[2026,8,29]],"date-time":"2026-08-29T12:08:58Z","timestamp":1788005338000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Conformation\u2010Locking in Thiazole\u2010Rich Mixed\u2010Linkage Covalent Organic Frameworks for Spontaneous Exciton Dissociation and Efficient Photocatalysis"],"prefix":"10.1002","volume":"65","author":[{"given":"Liujun","family":"Yang","sequence":"first","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xu","family":"Zhang","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering City University of Hong Kong  Hong Kong SAR P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chenfan","family":"Xie","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Long","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiangyue","family":"Wang","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Qiang","family":"Cao","sequence":"additional","affiliation":[{"name":"Cangzhou Risun Chemicals Co. Ltd.  Cangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junwei","family":"Yuan","sequence":"additional","affiliation":[{"name":"School of Chemistry and Life Sciences Suzhou University of Science and Technology  Suzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chen","family":"Yu","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Liren","family":"Gu","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0740-8397","authenticated-orcid":false,"given":"Zhigang","family":"Ren","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0982-5573","authenticated-orcid":false,"given":"Hua","family":"Li","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2451-7154","authenticated-orcid":false,"given":"Jianmei","family":"Lu","sequence":"additional","affiliation":[{"name":"College of Chemistry, Chemical Engineering and Materials Science Soochow University  Suzhou P. R. China"},{"name":"Suzhou Laboratory  Suzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,8,29]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44286\u2010025\u201000349\u2010w"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010025\u201001834\u20105"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010025\u201000908\u20102"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202511322"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202506509"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6c02198"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c19922"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202302837"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE01808G"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202516937"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202417712"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201904904"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202413060"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057662\u20104"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202105156"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1073\/pnas.2202913119"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201063590\u20100"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5CY01337B"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202523220"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202503929"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2025.125932"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2025.125292"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202526519"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201056103\u20106"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.apcatb.2026.127222"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.5c01163"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201038884\u2010w"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c21545"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201070161\u20104"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201058839\u20107"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1039\/c8cs00978c"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1039\/d5gc05287d"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202511245"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201067058\u2010z"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202516235"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1016\/s1872\u20102067(21)63966\u20109"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.8b08282"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c03418"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201067467\u20100"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202503792"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c04244"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202500937"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202415126"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/acscatal.2c02173"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202513848"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010021\u201024179\u20105"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202505986"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201051878\u20106"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202304697"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202422291"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c15825"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202517694"},{"key":"e_1_2_8_53_2","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202517694"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201062937\u2010x"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202517694"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010018\u201004979\u2010y"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202306758"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010021\u201000605\u20101"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201049373\u2010z"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202421623"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/ange.202501869"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.6c09675"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c22625"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201060960\u20106"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201062286\u20109"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010026\u201001045\u20100"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057166\u20101"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202406310"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202309480"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010023\u201040991\u20107"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201049663\u20106"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201066852\u2010z"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202401579"},{"key":"e_1_2_8_74_1","doi-asserted-by":"publisher","DOI":"10.1038\/s44160\u2010024\u201000644\u2010z"},{"key":"e_1_2_8_75_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201069549\u2010z"},{"key":"e_1_2_8_76_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010017\u201000585\u20106"},{"key":"e_1_2_8_77_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c12339"},{"key":"e_1_2_8_78_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41893\u2010025\u201001538\u20104"},{"key":"e_1_2_8_79_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201063838\u20109"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.4914496","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.4914496","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.4914496","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,17]],"date-time":"2026-10-17T17:40:35Z","timestamp":1792258835000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.4914496"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,8,29]]},"references-count":79,"journal-issue":{"issue":"43","published-print":{"date-parts":[[2026,10,19]]}},"alternative-id":["10.1002\/anie.4914496"],"URL":"https:\/\/doi.org\/10.1002\/anie.4914496","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,8,29]]},"assertion":[{"value":"2026-05-20","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-23","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-08-29","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e4914496"}}