{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,21]],"date-time":"2026-10-21T21:49:02Z","timestamp":1792619342491,"version":"4.5.0"},"reference-count":45,"publisher":"Wiley","issue":"36","license":[{"start":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T00:00:00Z","timestamp":1782777600000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T00:00:00Z","timestamp":1782777600000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22408054"],"award-info":[{"award-number":["22408054"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22378074"],"award-info":[{"award-number":["22378074"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22179025"],"award-info":[{"award-number":["22179025"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22508047"],"award-info":[{"award-number":["22508047"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100021171","name":"Basic and Applied Basic Research Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2025A1515011939"],"award-info":[{"award-number":["2025A1515011939"]}],"id":[{"id":"10.13039\/501100021171","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,9,1]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Lithium\u2010sulfur (Li\u2010S) batteries are attractive for next\u2010generation energy storage, yet practical deployment is impeded by the lithium polysulfides (LiPSs) shuttle effect and sluggish sulfur redox kinetics, which are further aggravated by solvent shielding that blocks LiPSs from accessing catalytic sites. Here, we develop a yolk\u2010shell MoO\n                    <jats:sub>3<\/jats:sub>\n                    \/Co\n                    <jats:sub>3<\/jats:sub>\n                    O\n                    <jats:sub>4<\/jats:sub>\n                    @C nanoreactor that leverages oxygen bridge\u2010induced orbital oscillation to break the solvation barrier and accelerate interfacial conversion. We identify that the dynamic vibration of Mo\u2010O\u2010Co oxygen bridges facilitates a directional electron flow via a 4\n                    <jats:italic>d<\/jats:italic>\n                    \u20102\n                    <jats:italic>p<\/jats:italic>\n                    \u20103\n                    <jats:italic>d<\/jats:italic>\n                    orbital interaction pathway, which fundamentally triggers a low\u2010spin to high\u2010spin transition of Co centers, strengthening\n                    <jats:italic>d<\/jats:italic>\n                    \u2010\n                    <jats:italic>p<\/jats:italic>\n                    orbital hybridization and enabling robust chemisorption\/catalysis of LiPSs. Meanwhile, the modulation of solvation structure from solvent\u2010separated ion pairs (SSIPs) to contact ion pairs (CIPs)\/aggregates (AGGs) lowers the Li\n                    <jats:sup>+<\/jats:sup>\n                    desolvation energy barrier and homogenizes the ion flux. Synergistically, the double\u2010shelled architecture confines soluble intermediates and suppresses outward diffusion. Consequently, Li\u2010S batteries deliver 352\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at an ultrahigh rate of 15 C, and an initial areal capacity of 11.95\u00a0mAh\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    is achieved at an ultrahigh sulfur loading of 13.03\u00a0mg\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . This work proposes a strategy of oxygen\u2010bridge\u2010induced high\u2010spin state to realize desolvation and mass\u2010transfer reaction of LiPSs within interface catalytic domain.\n                  <\/jats:p>","DOI":"10.1002\/anie.4944842","type":"journal-article","created":{"date-parts":[[2026,6,30]],"date-time":"2026-06-30T07:43:36Z","timestamp":1782805416000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Oxygen Bridge\u2010Induced Spin\u2010State Engineering Enables Solvation\u2010Barrier\u2010Free Sulfur Redox Kinetics in Lithium\u2010Sulfur Batteries"],"prefix":"10.1002","volume":"65","author":[{"given":"Jingjing","family":"Tian","sequence":"first","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zihao","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou People's Republic of China"},{"name":"Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center (Rongjiang Laboratory)  Jieyang People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tiyang","family":"Xiao","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zexin","family":"Su","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tong","family":"Li","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Junhao","family":"Li","sequence":"additional","affiliation":[{"name":"School of Environmental and Chemical Engineering Foshan University  Foshan People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2750-2188","authenticated-orcid":false,"given":"Ying","family":"Song","sequence":"additional","affiliation":[{"name":"Key Laboratory of Advanced Structural Materials Ministry of Education School of Materials Science and Engineering Changchun University of Technology  Changchun People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1900-2327","authenticated-orcid":false,"given":"Kaixiang","family":"Shi","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou People's Republic of China"},{"name":"Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center (Rongjiang Laboratory)  Jieyang People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3239-1539","authenticated-orcid":false,"given":"Lutong","family":"Shan","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering National University of Singapore  Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1889-989X","authenticated-orcid":false,"given":"Quanbing","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemical Engineering and Light Industry Guangdong University of Technology  Guangzhou People's Republic of China"},{"name":"Guangdong Provincial Laboratory of Chemistry and Fine Chemical Engineering Jieyang Center (Rongjiang Laboratory)  Jieyang People's Republic of China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,6,30]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201063969\u2010z"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41586\u2010023\u201006918\u20104"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.72365"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c13776"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE05654C"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202516197"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202510368"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/advs.202513049"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ces.2023.119236"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202410517"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202311750"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.162147"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202303546"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsaem.5c03059"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202407070"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202515380"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202504046"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5b04472"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.201900219"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202102819"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202304120"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202209233"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202402114"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202407741"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202502075"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202409303"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c07213"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE03213J"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202425138"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202105947"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2024.103657"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202406065"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202500950"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202505615"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c16469"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c13298"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202514402"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c05595"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c14250"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202511910"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202510516"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c10841"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c11688"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c14801"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c10684"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.4944842","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.4944842","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.4944842","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,10,15]],"date-time":"2026-10-15T14:54:42Z","timestamp":1792076082000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.4944842"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,6,30]]},"references-count":45,"journal-issue":{"issue":"36","published-print":{"date-parts":[[2026,9,1]]}},"alternative-id":["10.1002\/anie.4944842"],"URL":"https:\/\/doi.org\/10.1002\/anie.4944842","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,6,30]]},"assertion":[{"value":"2026-02-26","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-12","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-06-30","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e4944842"}}