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Although traditional scintillators have shown great potential in object imaging, they are often unable to capture thermal signals. In this work, a series of Tb\n                    <jats:sup>3+<\/jats:sup>\n                    \/Eu\n                    <jats:sup>3+<\/jats:sup>\n                    co\u2010doped MOF\u2010based scintillators (\n                    <jats:bold>\n                      Tb\n                      <jats:sub>x<\/jats:sub>\n                      Eu\n                      <jats:sub>(1\u2013x)<\/jats:sub>\n                    <\/jats:bold>\n                    ) were developed with exceptional F\u00f6rster resonance energy transfer from Tb\n                    <jats:sup>3+<\/jats:sup>\n                    to Eu\n                    <jats:sup>3+<\/jats:sup>\n                    . Crucially, a distinctive structural relaxation occurs at 440\u00a0K in\n                    <jats:bold>\n                      Tb\n                      <jats:sub>x<\/jats:sub>\n                      Eu\n                      <jats:sub>(1\u2013x)<\/jats:sub>\n                    <\/jats:bold>\n                    , which activates a specific phonon mode to dissipate the excess energy from Tb\n                    <jats:sup>3+<\/jats:sup>\n                    (\n                    <jats:sup>5<\/jats:sup>\n                    <jats:italic>D<\/jats:italic>\n                    <jats:sub>4<\/jats:sub>\n                    ) to Eu\n                    <jats:sup>3+<\/jats:sup>\n                    (\n                    <jats:sup>5<\/jats:sup>\n                    <jats:italic>D<\/jats:italic>\n                    <jats:sub>1<\/jats:sub>\n                    ). The abrupt weakening of coordination interaction and subsequent lattice softening above 440 K trigger the release of vibrational freedom and the increase of phonon population, leading to pronounced energy transfer efficiency enhancement and temperature\u2010dependent luminescent color shift. Leveraging the unique high\u2010temperature responsiveness and superior scintillation performance of\n                    <jats:bold>\n                      Tb\n                      <jats:sub>0.99<\/jats:sub>\n                      Eu\n                      <jats:sub>0.01<\/jats:sub>\n                    <\/jats:bold>\n                    , the developed\n                    <jats:bold>\n                      Tb\n                      <jats:sub>0.99<\/jats:sub>\n                      Eu\n                      <jats:sub>0.01<\/jats:sub>\n                      \u2010screen\n                    <\/jats:bold>\n                    enables simultaneous capture of x\u2010ray imaging and thermal signals, which provides a new approach for achieving precise structural observation of electronic components and spatial localization of the abnormal overheating zone.\n                  <\/jats:p>","DOI":"10.1002\/anie.5028581","type":"journal-article","created":{"date-parts":[[2026,8,22]],"date-time":"2026-08-22T09:12:36Z","timestamp":1787389956000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Structural Relaxation Modulated Phonon\u2010Assisted Energy Transfer Scintillator for Simultaneous X\u2010Ray Imaging and Thermal Signals Visualization"],"prefix":"10.1002","volume":"65","author":[{"given":"Peng\u2010Kun","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Structural Chemistry Fujian Institute of Research on the Structure of Matter Chinese Academy of Sciences  Fuzhou Fujian P. 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