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Enhancement of dynamic SF\n                    <jats:sub>6<\/jats:sub>\n                    capture capacity presents significant challenges due to its chemical inertness and low concentration in industrial effluent streams. Herein, we demonstrate that the isoreticular functionalization of zinc\u2010pyrazolate metal\u2010organic frameworks (MOFs) enables simultaneous enhancement of both SF\n                    <jats:sub>6<\/jats:sub>\n                    adsorption capacity and uptake kinetics. Through replacement of benzene with pyridine in the ligand, BUT\u2010125 (BUT: Beijing University of Technology) achieves a record\u2010high SF\n                    <jats:sub>6<\/jats:sub>\n                    adsorption capacity of 3.57\u00a0mmol cm\n                    <jats:sup>\u22123<\/jats:sup>\n                    at 0.1\u00a0bar and 298 K, representing a 27% improvement over its structural analogue Zn\u2010DPB (DPB: 1,3\u2010di(pyrazolate\u20104\u2010yl)benzene). Density functional theory (DFT) calculations reveal that pyridine functionalization increases the positive charge density on hydrogen atoms within molecular trap sites, strengthening C\u2500H\u00b7\u00b7\u00b7F interactions with SF\n                    <jats:sub>6<\/jats:sub>\n                    molecules. Remarkably, BUT\u2010125 also exhibits outstanding adsorption kinetics, that combined with high equilibrium uptake, leads to an exceptional dynamic SF\n                    <jats:sub>6<\/jats:sub>\n                    capture capacity of 3.42\u00a0mmol cm\n                    <jats:sup>\u22123<\/jats:sup>\n                    from the SF\n                    <jats:sub>6<\/jats:sub>\n                    \/N\n                    <jats:sub>2<\/jats:sub>\n                    (10\/90) mixture, surpassing reported porous sorbents.\n                  <\/jats:p>","DOI":"10.1002\/anie.5036296","type":"journal-article","created":{"date-parts":[[2026,1,29]],"date-time":"2026-01-29T06:18:26Z","timestamp":1769667506000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":14,"title":["Simultaneous Boost of SF\n                    <sub>6<\/sub>\n                    Adsorption Capacity and Kinetics Through Isoreticular Functionalization of Zinc(II)\u2010Pyrazolate Frameworks"],"prefix":"10.1002","volume":"65","author":[{"given":"Xiang\u2010Yu","family":"Li","sequence":"first","affiliation":[{"name":"State Key Laboratory of Materials Low\u2010Carbon Recycling Department of Chemical Engineering College of Materials Science &amp; Engineering Beijing University of Technology  Beijing PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yan\u2010Long","family":"Zhao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Low\u2010Carbon Recycling Department of Chemical Engineering College of Materials Science &amp; Engineering Beijing University of Technology  Beijing PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9318-8839","authenticated-orcid":false,"given":"Xin","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Low\u2010Carbon Recycling Department of Chemical Engineering College of Materials Science &amp; Engineering Beijing University of Technology  Beijing PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xuefeng","family":"Bai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Low\u2010Carbon Recycling Department of Chemical Engineering College of Materials Science &amp; Engineering Beijing University of Technology  Beijing PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Muzi","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Materials Low\u2010Carbon Recycling Department of Chemical Engineering College of Materials Science &amp; Engineering Beijing University of Technology  Beijing PR China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8101-8493","authenticated-orcid":false,"given":"Jian\u2010Rong","family":"Li","sequence":"additional","affiliation":[{"name":"State Key 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