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However, their practical application is severely hindered by Na dendrite formation coupled with aggressive CO\n                    <jats:sub>2<\/jats:sub>\n                    electro\u2010\/chemical corrosion, and extremely low Na anode utilization rates. This study addresses these interconnected challenges by employing a multifunctional covalent organic framework (COF) coating. Specifically, the C\n                    <jats:sub>6<\/jats:sub>\n                    O\n                    <jats:sub>6<\/jats:sub>\n                    \u2010TAPT COF features a fully conjugated skeleton for rapid electron cloud response, abundantly distributed sodiophilic chelation sites (C\u2550O and C\u2550N) for Na\n                    <jats:sup>+<\/jats:sup>\n                    capture, and ordered AB stacked structure for homogenizing Na\n                    <jats:sup>+<\/jats:sup>\n                    flux. The COMSOL simulations further demonstrate the stress\u2010regulating strategy in mitigate solid electrolyte interphase (SEI) cracking and separator puncturing risks. Consequently, Na\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    batteries using the designed industrial\u2010scale anode achieve low polarization (1.4\u00a0V) and sustain stable cycling for over 1100\u00a0h at 100\u00a0mA g\n                    <jats:sup>\u22121<\/jats:sup>\n                    across 0\u201360\u00a0\u00b0C. Remarkably, it maintained over 100 cycles at reduced N\/P of 10 and delivered a high discharge capacity of 11552\u00a0mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    under lean electrolyte conditions (8.7\u00a0\u00b5L mAh\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). This study validates stable and functionalized COF substrates with dendrite suppression capability in Na\u2010CO\n                    <jats:sub>2<\/jats:sub>\n                    batteries, proposing a scalable pathway with implications for next\u2010generation energy storage.\n                  <\/jats:p>","DOI":"10.1002\/anie.5076332","type":"journal-article","created":{"date-parts":[[2026,9,12]],"date-time":"2026-09-12T17:16:41Z","timestamp":1789233401000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Regulating Sodium Deposition Behavior via Polar Functional Group\u2010Based Interfacial Engineering on an Industrial\u2010Scale Anode for High\u2010Performance Na\u2010CO\n                    <sub>2<\/sub>\n                    Batteries"],"prefix":"10.1002","author":[{"given":"Hanqi","family":"Zhang","sequence":"first","affiliation":[{"name":"School of Chemistry Engineering Research Center of Energy Storage Materials and Devices Ministry of Education Xi'an Jiaotong University  ShaanXi P. 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