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However, small\u2010molecule organic electrode materials suffer from sluggish ion diffusion and high dissolution in electrolytes, limiting their practical applications. Here we present sulfur\u2010heterocyclic extension of redox\u2010active triptycene tribenzoquinone monomers, enabling two\u2010dimensional supramolecular polymerization to yield porous multilayer nanosheets with architectural robustness. This supramolecular engineering achieves rapid and stable lithium (Li) storage through cross\u2010flow ion transport dominated by pseudocapacitance. At a current density of 18 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , a power\u2010densed organic cathode (\u223c42 kW kg\n                    <jats:sup>\u22121<\/jats:sup>\n                    ) reaches 76% state\u2010of\u2010charge (SoC) only in 44 seconds while retaining 79% of its capacity over 5,000 cycles. Its superior high\u2010rate performance and cycling stability persist even under cryogenic conditions. We demonstrate its practicability with a Li\u2013organic pouch cell featuring a high areal capacity of 5 mAh cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    and 6C\u2010charging capability to 66% SoC, which fully meets the performance metrics of practical fast\u2010charging Li\u2010ion batteries.\n                  <\/jats:p>","DOI":"10.1002\/anie.5096270","type":"journal-article","created":{"date-parts":[[2026,7,13]],"date-time":"2026-07-13T17:30:22Z","timestamp":1783963822000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Fast\u2010Charging and Durable Organic Cathodes Enabled by Two\u2010Dimensional Supramolecular Polymerization"],"prefix":"10.1002","volume":"65","author":[{"given":"Li","family":"Liu","sequence":"first","affiliation":[{"name":"Institute of Materials Research Tsinghua Shenzhen International Graduate School Tsinghua University  Shenzhen China"},{"name":"School of 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