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Visible\u2010light irradiation has emerged as a mild and sustainable energy input for generating such radical species. Most photo\u2010induced radical generation methods have relied on photocatalysts or substrates that absorb high\u2010energy light. Increasing attention has been directed toward photochemical reactions driven by deep\u2010red (DR) to near\u2010infrared (NIR) light through the development of chromophores and catalytic systems capable of harvesting low\u2010energy photons. Compared with short\u2010wavelength light\u2010driven processes, NIR light\u2010mediated reactions offer distinct advantages, including enhanced penetration through biological tissues and reduced unwanted excitation of intermediates, thereby suppressing side reactions. Nevertheless, the intrinsically low energy of NIR photons imposes fundamental challenges, limiting the scope of accessible transformations. 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