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It is widely accepted that the in\u2010plane sulfur vacancies are the active sites for methanol formation, while the edge sulfur vacancies catalyze methane formation, which is typically undesirable. Rather than blocking the edge sites with heteroatom dopants, we demonstrate that decorating the edges of MoS\n                    <jats:sub>2<\/jats:sub>\n                    with functional FeO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    clusters effectively boost methanol formation via synergy between the RWGS activity of the anchored FeO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    clusters and the CO hydrogenation activity of the in\u2010plane sulfur vacancies. Synthetically, this was achieved by a vacuum impregnation method that chemically anchors FeO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    clusters on the edges of MoS\n                    <jats:sub>2<\/jats:sub>\n                    , forming stable Fe\u2010S\/Fe\u2010O interfaces. With these Fe\u2010S\/Fe\u2010O interfaces, the Fe\/MoS\n                    <jats:sub>2<\/jats:sub>\n                    catalyst shows markedly enhanced methanol selectivity (to 80%) and a high intrinsic space\u2010time\u2010yield (STY) of 0.6 mmol\n                    <jats:sub>CH3OH<\/jats:sub>\n                    \u00b7m\n                    <jats:sup>\u22122<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    . In situ spectroscopic and microscopic characterizations combined with theoretical calculations corroborate that the formation of amorphous FeO\n                    <jats:italic>\n                      <jats:sub>x<\/jats:sub>\n                    <\/jats:italic>\n                    clusters at edge sites of MoS\n                    <jats:sub>2<\/jats:sub>\n                    could effectively suppress edge S\n                    <jats:italic>\n                      <jats:sub>v<\/jats:sub>\n                    <\/jats:italic>\n                    formation, generate additional CO\n                    <jats:sup>*<\/jats:sup>\n                    , and promote the formation of methanol at the in\u2010plane S\n                    <jats:italic>\n                      <jats:sub>v<\/jats:sub>\n                    <\/jats:italic>\n                    sites. Broadly speaking, this work has demonstrated the modulation of MoS\n                    <jats:sub>2<\/jats:sub>\n                    edge sites using simple and scalable catalyst preparation methods to enhance methanol formation.\n                  <\/jats:p>","DOI":"10.1002\/anie.5129158","type":"journal-article","created":{"date-parts":[[2026,5,27]],"date-time":"2026-05-27T14:05:56Z","timestamp":1779890756000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Synergistic Enhancement of Methanol Formation by Edge\u2010Site FeO\n                    <i>\n                      <sub>x<\/sub>\n                    <\/i>\n                    Clusters and In\u2010Plane Vacancies on MoS\n                    <sub>2<\/sub>\n                    for CO\n                    <sub>2<\/sub>\n                    Hydrogenation"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-4029-5283","authenticated-orcid":false,"given":"Huibo","family":"Zhao","sequence":"first","affiliation":[{"name":"School of Chemistry Chemical Engineering and Biotechnology Nanyang Technological University  Singapore"},{"name":"Cambridge Centre for Advanced Research and Education in Singapore  Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenrui","family":"Ma","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biomolecular Engineering College of Design and Engineering National University of Singapore  Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenjie","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Chemistry Chemical Engineering and Biotechnology Nanyang Technological University  Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiabin","family":"Niu","sequence":"additional","affiliation":[{"name":"Agency for Science Technology and Research (A*STAR) Institute of Sustainability for Chemicals Energy and Environment  Jurong Island Singapore"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9818-4607","authenticated-orcid":false,"given":"Chuande","family":"Huang","sequence":"additional","affiliation":[{"name":"CAS Key Laboratory of Science and Technology on Applied Catalysis Dalian Institute of Chemical Physics Chinese Academy of Sciences  Dalian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yao","family":"Wu","sequence":"additional","affiliation":[{"name":"Department of Materials Science and Engineering College of Design and Engineering National University of Singapore  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