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Here we establish a programmable strategy for constructing selenium\u2010based molybdenum chalcoxides using the [Mo\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    Se\n                    <jats:sub>2<\/jats:sub>\n                    ]\n                    <jats:sup>2+<\/jats:sup>\n                    dimer as a universal building block. The template\u2010directed assembly process produces a complete family of ring architectures (\n                    <jats:italic>n<\/jats:italic>\n                    = 8\u201316), with nuclearity encoded by the template's geometry and acidity. Selenium incorporation introduces electronic softness that imparts unusual structural flexibility and enables adaptive behaviour. NMR titration experiments reveal host\u2013guest exchange in solution, demonstrating dynamic recognition in these purely inorganic rings. This family of clusters also displays tuneable electrocatalytic hydrogen evolution activity (HER), following the trend Mo\n                    <jats:sub>8<\/jats:sub>\n                    &gt; Mo\n                    <jats:sub>12<\/jats:sub>\n                    &gt; Mo\n                    <jats:sub>10<\/jats:sub>\n                    and consistently outperforming their sulphur analogues. Together, these results define a design framework in which modular assembly, dynamic function, and catalytic activity arise from a common chalcogen\u2010dependent structural logic, opening new avenues for responsive inorganic molecular materials.\n                  <\/jats:p>","DOI":"10.1002\/anie.5129627","type":"journal-article","created":{"date-parts":[[2026,9,30]],"date-time":"2026-09-30T05:25:51Z","timestamp":1790745951000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Template\u2010Encoded Assembly and Adaptive Function in Selenium\u2010Based Molybdenum Chalcoxide Rings"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-1519-5765","authenticated-orcid":false,"given":"Giulia","family":"Pellegrino","sequence":"first","affiliation":[{"name":"School of Chemistry The University of Glasgow  Glasgow UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alexander","family":"Elliott","sequence":"additional","affiliation":[{"name":"School of Chemistry The University of Glasgow  Glasgow UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1309-0626","authenticated-orcid":false,"given":"Yu\u2010Fei","family":"Song","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemical Resource Engineering Beijing Advanced Innovation Centre for Soft Matter Science and Engineering Beijing University of Chemical Technology  Beijing China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5754-7328","authenticated-orcid":false,"given":"Nuno A. 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