{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T04:08:20Z","timestamp":1790136500980,"version":"4.0.1"},"reference-count":75,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T00:00:00Z","timestamp":1790035200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22371047"],"award-info":[{"award-number":["22371047"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22201042"],"award-info":[{"award-number":["22201042"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Crown ether\u2010regulated metal halides feature programmable host\u2010guest coordination and structurally defined emissive centers, making them promising for multifunctional scintillation applications. However, their strong coordination and supramolecular interactions favor ordered assembly and crystallization, hindering melt\u2010processing into large\u2010area, transparent glassy scintillator screens. Here, we develop a \u201cthree birds with one stone\u201d strategy using sandwich\u2010like benzo\u201015\u2010crown\u20105\u2010metal supramolecular clamps to simultaneously regulate [MnBr\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>2\u2212<\/jats:sup>\n                    geometry, cation\u2010associated charge collection, and glass formation. Four Mn(II) bromides, [(B15C5)\n                    <jats:sub>2<\/jats:sub>\n                    @K]\n                    <jats:sub>2<\/jats:sub>\n                    MnBr\n                    <jats:sub>4<\/jats:sub>\n                    (CKMB), [(B15C5)\n                    <jats:sub>2<\/jats:sub>\n                    @Rb]\n                    <jats:sub>2<\/jats:sub>\n                    MnBr\n                    <jats:sub>4<\/jats:sub>\n                    (CRMB), [(B15C5)\n                    <jats:sub>2<\/jats:sub>\n                    @Sr]MnBr\n                    <jats:sub>4<\/jats:sub>\n                    (CSMB), and [(B15C5)\n                    <jats:sub>2<\/jats:sub>\n                    @Ba]MnBr\n                    <jats:sub>4<\/jats:sub>\n                    (CBMB), were obtained. The well\u2010matched K\n                    <jats:sup>+<\/jats:sup>\n                    \u2010B15C5 clamp stabilizes a nearly ideal [MnBr\n                    <jats:sub>4<\/jats:sub>\n                    ]\n                    <jats:sup>2\u2212<\/jats:sup>\n                    tetrahedron in CKMB, affording a photoluminescence quantum yield of 82.2%. The cationic framework contributes to the conduction\u2010band\u2010edge states and promotes X\u2010ray charge collection, yielding a relative light yield of 6.74 \u00d7 10\n                    <jats:sup>4<\/jats:sup>\n                    photons MeV\n                    <jats:sup>\u22121<\/jats:sup>\n                    and a detection limit of 28.5 nGy s\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Meanwhile, monovalent clamp cations induce steric mismatch and packing frustration, enabling vitrification of CKMB and CRMB. CKMB\u2010G exhibits T\n                    <jats:sub>g<\/jats:sub>\n                    = 61\u00b0C, T\n                    <jats:sub>g<\/jats:sub>\n                    \/T\n                    <jats:sub>m<\/jats:sub>\n                    = 0.87, and a retained light yield of 3.20 \u00d7 10\n                    <jats:sup>4<\/jats:sup>\n                    photons MeV\n                    <jats:sup>\u22121<\/jats:sup>\n                    . The complementary crystalline and glassy states enable WLED emission, X\u2010ray imaging at 32 lp mm\n                    <jats:sup>\u22121<\/jats:sup>\n                    , dynamic imaging at 2K resolution and 60 fps, and multimodal anti\u2010counterfeiting, highlighting supramolecular clamps as active cationic templates for multifunctional Mn(II) scintillators.\n                  <\/jats:p>","DOI":"10.1002\/anie.5230240","type":"journal-article","created":{"date-parts":[[2026,9,23]],"date-time":"2026-09-23T03:41:36Z","timestamp":1790134896000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Sandwich\u2010Like Supramolecular Clamp\u2010Templated Manganese(II) Bromide Scintillators for Multimodal Visualization"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0463-5145","authenticated-orcid":false,"given":"Yuan\u2010Ji","family":"Ye","sequence":"first","affiliation":[{"name":"State Key Laboratory of Fluorine &amp; Nitrogen Chemicals, College of Chemical Engineering Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hui\u2010E","family":"Lin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fluorine &amp; Nitrogen Chemicals, College of Chemistry Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yue\u2010Chen","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fluorine &amp; Nitrogen Chemicals, College of Chemistry Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tong","family":"Xiao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fluorine &amp; Nitrogen Chemicals, College of Materials Science and Engineering Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Shu\u2010Quan","family":"Zhang","sequence":"additional","affiliation":[{"name":"College of Zhicheng Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ming\u2010Hua","family":"You","sequence":"additional","affiliation":[{"name":"Institute of Biology and Chemistry Fujian University of Technology  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1231-7331","authenticated-orcid":false,"given":"Hong\u2010Ming","family":"Chen","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fluorine &amp; Nitrogen Chemicals, College of Materials Science and Engineering Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7694-7634","authenticated-orcid":false,"given":"Zai\u2010Lai","family":"Xie","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fluorine &amp; Nitrogen Chemicals, College of Chemistry Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2008-9674","authenticated-orcid":false,"given":"Mei\u2010Jin","family":"Lin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Fluorine &amp; Nitrogen Chemicals, College of Chemical Engineering Fuzhou University  Fuzhou China"},{"name":"State Key Laboratory of Fluorine &amp; Nitrogen Chemicals, College of Chemistry Fuzhou University  Fuzhou China"},{"name":"State Key Laboratory of Fluorine &amp; Nitrogen Chemicals, College of Materials Science and Engineering Fuzhou University  Fuzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,22]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1021\/acs.accounts.2c00517","article-title":"Advancing X\u2010ray Luminescence for Imaging, Biosensing, and Theragnostics","volume":"56","author":"Hong Z.","year":"2023","journal-title":"Accounts of Chemical Research"},{"key":"e_1_2_8_3_1","doi-asserted-by":"crossref","DOI":"10.1002\/adma.202303611","article-title":"Strong Magnetically\u2010Responsive Circularly Polarized Phosphorescence and X\u2010ray Scintillation in Ultrarobust Mn(II)\u2013Organic Helical Chains","volume":"35","author":"Davydova M. 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