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The uniformity of the framework structure facilitated the synthesis of MTV\u2010MOFs with 2, 4, 12, 15, or 16 (including In(III)) different metals. Single crystal structures of each unimetallic MOFs and MTV\u2010MOFs with 12 or 16 metals were determined, confirming the isoreticular nature of this family of MOFs. Energy Dispersive X\u2010ray (EDX) analysis confirmed distribution of each metal throughout crystals of the MTV\u2010MOFs and compositional analysis indicated increased concentration of lanthanides with smaller cationic radius. A protocol was developed to control relative composition in bimetallic systems,\n                    <jats:bold>\n                      UoB\u2010116(La\n                      <jats:sub>1\u2010x<\/jats:sub>\n                      Lu\n                      <jats:sub>x<\/jats:sub>\n                      )\n                    <\/jats:bold>\n                    and\n                    <jats:bold>\n                      UoB\u2010116(Dy\n                      <jats:sub>1\u2010x<\/jats:sub>\n                      La\n                      <jats:sub>x<\/jats:sub>\n                      )\n                    <\/jats:bold>\n                    (\n                    <jats:italic>x<\/jats:italic>\n                    = 0\u20131). In the case of\n                    <jats:bold>\n                      UoB\u2010116(Dy\n                      <jats:sub>1\u2010x<\/jats:sub>\n                      La\n                      <jats:sub>x<\/jats:sub>\n                      )\n                    <\/jats:bold>\n                    it is shown that the porosity, magnetism and UV\u2013visible properties can be tuned through metal cation composition.\n                  <\/jats:p>","DOI":"10.1002\/anie.5287849","type":"journal-article","created":{"date-parts":[[2026,9,26]],"date-time":"2026-09-26T12:09:39Z","timestamp":1790424579000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Rare\u2010Earth Multivariate Metal\u2013Organic Frameworks: Cationic Radius Biased Compositional Control and Property Tuning"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-2735-1300","authenticated-orcid":false,"given":"Adnan","family":"Ishaq","sequence":"first","affiliation":[{"name":"School of Chemistry University of Birmingham  Edgbaston Birmingham UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2115-2885","authenticated-orcid":false,"given":"Joseph O.","family":"Ogar","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Nottingham  Nottingham UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7140-8543","authenticated-orcid":false,"given":"Asif","family":"Raza","sequence":"additional","affiliation":[{"name":"Bernal Institute and Research Ireland Centre for Pharmaceuticals (SSPC), Department of Chemical Sciences University of Limerick  Limerick Ireland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5041-1850","authenticated-orcid":false,"given":"Musa M.","family":"Mahmud","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Birmingham  Edgbaston Birmingham UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0009-6724-2710","authenticated-orcid":false,"given":"Jacob L.","family":"Brownlee","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Birmingham  Edgbaston Birmingham UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Danielle E.","family":"Schier","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Birmingham  Edgbaston Birmingham UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3461-9675","authenticated-orcid":false,"given":"Stephen P.","family":"Argent","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Nottingham  Nottingham UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6223-3622","authenticated-orcid":false,"given":"Lucy","family":"Clark","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Birmingham  Edgbaston Birmingham UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2375-7009","authenticated-orcid":false,"given":"Soumya","family":"Mukherjee","sequence":"additional","affiliation":[{"name":"Bernal Institute and Research Ireland Centre for Pharmaceuticals (SSPC), Department of Chemical Sciences University of Limerick  Limerick Ireland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2970-1487","authenticated-orcid":false,"given":"Neil 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