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Here, we report a dual\u2010functional design that integrates amorphous nanostructuring with water\u2010triggered self\u2010coordinated crystallization to produce scalable, stable surfactant\u2010free MOF nanocatalysts. An amorphous pyridyl\u2010porphyrinic precursor is first prepared as hexagonal nanosheets via an ultrasonic\u2010assisted process. Upon exposure to water, cyclic hexameric water clusters bind pyridyl sites and drive reorganization into a corner\u2010sharing porphyrinic\u2010hexagon 3D honeycomb lattice, yielding robust hexagonal nanorods. Confined water clusters stabilize the lattice for &gt;2 months and generate a pronounced potential gradient that promotes charge separation. The resulting nanocatalysts achieve a hydrogen evolution rate of 223.81\u00a0mmol g\n                    <jats:sup>\u22121<\/jats:sup>\n                    h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , representing one of the better values reported for molecular photocatalysts. This work introduces water\u2010cluster\u2013induced amorphous\u2010to\u2010crystalline self\u2010assembly as a versatile strategy for stabilizing surfactant\u2010free MOF nanophotocatalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.5372883","type":"journal-article","created":{"date-parts":[[2026,3,9]],"date-time":"2026-03-09T07:20:26Z","timestamp":1773040826000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Water\u2010Cluster\u2013Mediated Amorphous\u2010to\u2010Crystalline Transition Enables Scalable Fabrication of Stable Surfactant\u2010Free MOF Nanocatalyst"],"prefix":"10.1002","volume":"65","author":[{"given":"Ran","family":"Wang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Runmin","family":"Dong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xijiao","family":"Mu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Chen","family":"Lu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yongping","family":"Yang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou China"},{"name":"Center For Hydrogen Energy and Low Carbon Lanzhou University  Lanzhou China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3978-911X","authenticated-orcid":false,"given":"Jing","family":"Cao","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Natural Product Chemistry Key Laboratory of Nonferrous Metal Chemistry and Resources Utilization of Gansu Province College of Chemistry and Chemical Engineering Lanzhou University  Lanzhou China"},{"name":"Center For Hydrogen Energy and Low Carbon Lanzhou University  Lanzhou China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"311","published-online":{"date-parts":[[2026,3,9]]},"reference":[{"key":"e_1_2_7_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41929\u2010021\u201000665\u20103"},{"key":"e_1_2_7_3_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.chemrev.2c00587"},{"key":"e_1_2_7_4_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00095A"},{"key":"e_1_2_7_5_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2024.216381"},{"key":"e_1_2_7_6_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202523106"},{"key":"e_1_2_7_7_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.1230444"},{"key":"e_1_2_7_8_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201806077"},{"key":"e_1_2_7_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202307003"},{"key":"e_1_2_7_10_1","doi-asserted-by":"publisher","DOI":"10.1002\/eem2.12389"},{"key":"e_1_2_7_11_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202201779"},{"key":"e_1_2_7_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.201902229"},{"key":"e_1_2_7_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201061836\u20105"},{"key":"e_1_2_7_14_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ccr.2022.214542"},{"key":"e_1_2_7_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202014208"},{"key":"e_1_2_7_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/cr5002589"},{"key":"e_1_2_7_17_1","article-title":"Metal\u2013Organic Frameworks for Membrane\u2010Based Separations","volume":"1","author":"Denny M. 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