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However, severe halide\u2013sulfide interfacial incompatibility induces continuous interfacial degradation and undermines Li\n                    <jats:sup>+<\/jats:sup>\n                    transport. Unlike conventional interfacial engineering approaches that rely on coatings or artificial buffer layers, we report a local chemistry\u2013driven intrinsic compatibility strategy that fundamentally stabilizes halide\u2013sulfide interfaces. By sulfurizing amorphous halide electrolytes Li\n                    <jats:sub>2<\/jats:sub>\n                    O\u2013TaCl\n                    <jats:sub>5<\/jats:sub>\n                    , the short\u2010range coordination chemistry and medium\u2010range topology are simultaneously reconstructed, in which sulfur\u2010rich local motifs become thermodynamically more resistant to further sulfur substitution, whereas sulfur\u2010containing medium\u2010range networks exhibit stronger binding with PS\n                    <jats:sub>4<\/jats:sub>\n                    units in Li\n                    <jats:sub>6<\/jats:sub>\n                    PS\n                    <jats:sub>5<\/jats:sub>\n                    Cl, thereby intrinsically stabilizing the halide\u2013sulfide interface and suppressing interfacial decomposition. Simultaneously, the sulfurized framework exhibits enhanced structural heterogeneity and interconnected Li\n                    <jats:sup>+<\/jats:sup>\n                    migration pathways, achieving an ultrahigh ionic conductivity of 14.2\u00a0mS\u00a0cm\n                    <jats:sup>\u22121<\/jats:sup>\n                    . As a result, the assembled NCM89|8S\u2010LTOC|LPSC|Li\u2010In ASSBs exhibit outstanding electrochemical performance from \u221250\u00b0C to 100\u00b0C, including 131\u00a0mAh\u00a0g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at \u221250\u00b0C, 2000\u2010cycle stability at 15 C, and high areal capacities up to 21.7\u00a0mAh\u00a0cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . This work highlights local anion chemistry regulation as an effective strategy for developing robust halide\u2013sulfide ASSBs.\n                  <\/jats:p>","DOI":"10.1002\/anie.5372994","type":"journal-article","created":{"date-parts":[[2026,9,22]],"date-time":"2026-09-22T04:57:26Z","timestamp":1790053046000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Tailoring Local Anion Chemistry Affinity Enables Stable Halide\u2013Sulfide Interfaces and Fast Ion Transport in Dual\u2010Electrolyte all\u2010Solid\u2010State Batteries"],"prefix":"10.1002","author":[{"given":"Jie","family":"Qu","sequence":"first","affiliation":[{"name":"Eastern Institute for Advanced Study School of Material Science and Engineering Ningbo Key Laboratory of All\u2010Solid\u2010State Battery Zhejiang Key Laboratory of All\u2010Solid\u2010State Battery Eastern Institute of Technology  Ningbo Zhejiang P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xingyu","family":"Wang","sequence":"additional","affiliation":[{"name":"Eastern Institute for Advanced Study School of Material Science and Engineering Ningbo Key Laboratory of All\u2010Solid\u2010State Battery Zhejiang Key Laboratory of All\u2010Solid\u2010State Battery Eastern Institute of Technology  Ningbo Zhejiang P.R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7087-6372","authenticated-orcid":false,"given":"Huaimin","family":"Jin","sequence":"additional","affiliation":[{"name":"Eastern Institute for Advanced Study School of Material Science and Engineering Ningbo Key Laboratory of All\u2010Solid\u2010State Battery Zhejiang Key Laboratory of All\u2010Solid\u2010State Battery Eastern Institute of Technology  Ningbo Zhejiang P.R. 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