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However, designing catalysts that facilitate the selective generation of radicals while avoiding side reactions (such as over\u2010oxidation) remains a major challenge. Herein, we demonstrate the enhanced spin polarization and lattice oxygen migration on CoO\n                    <jats:sub>x<\/jats:sub>\n                    \/Fe\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>3<\/jats:sub>\n                    catalyst for cyclohexane oxidation under solvent\u2010free conditions. We introduce highly dispersed CoO\n                    <jats:sub>x<\/jats:sub>\n                    clusters on iron oxide nanorods (Co\/FeNR) through atomic layer deposition, forming interfacial Co\u2013O\u2013Fe active sites. The high\u2010spin Co atoms modulate the spin\u2010state of neighboring Fe atoms via double\u2010exchange interaction, promoting the adsorption and dissociation of triplet molecular oxygen. Meanwhile, Co effectively enhances the mobility of lattice oxygen, further forming the interface\u2010confined radical intermediate. Both spin polarization\u2010promoted oxygen activation and lattice oxygen migration drive the transformation of interface\u2010confined radicals, thus suppressing side reactions and enhancing selectivity. Benefiting from these effects, the 5Co\/FeNR achieves 14.6% conversion and 82.7% selectivity for KA oil and mass\u2010specific reaction rate of 830.7\u00a0mmol\u00b7g\n                    <jats:sub>cat<\/jats:sub>\n                    <jats:sup>\u22121<\/jats:sup>\n                    \u00b7h\n                    <jats:sup>\u22121<\/jats:sup>\n                    , which is approximately 6 times that of FeNR. This study provides valuable insights into the rational design of efficient oxidation catalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.5512890","type":"journal-article","created":{"date-parts":[[2026,5,30]],"date-time":"2026-05-30T11:53:47Z","timestamp":1780142027000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Evidence for Spin Polarization and Lattice Oxygen Migration During Cyclohexane Oxidation Over CoO\n                    <sub>x<\/sub>\n                    \/Fe\n                    <sub>2<\/sub>\n                    O\n                    <sub>3<\/sub>"],"prefix":"10.1002","volume":"65","author":[{"given":"Xixi","family":"Zhang","sequence":"first","affiliation":[{"name":"State Key Laboratory of Coal Conversion Institute of Coal Chemistry Chinese Academy of Sciences  Taiyuan China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  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Facility Shanghai Advanced Research Institute Chinese Academy of Sciences  Shanghai China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Conghui","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering Henan University of Technology  Zhengzhou China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3108-0384","authenticated-orcid":false,"given":"Yong","family":"Qin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Coal Conversion Institute of Coal Chemistry Chinese Academy of Sciences  Taiyuan China"},{"name":"Center of Materials Science and Optoelectronics Engineering University of Chinese Academy of Sciences  Beijing China"},{"name":"State Key Laboratory of Advanced Optical Polymer and Manufacturing Technology College of Materials Science and Engineering Qingdao University of Science and Technology  Qingdao 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