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Here, an iron\u2010chloride\u2010intercalated graphite \u00a0stabilized by oxygen functional groups is shown to establish a pre\u2010activated, cascade multi\u2010electron redox pathway. Sequential oxidation of iron and chlorine at intermediate potentials simultaneously expands interlayer spacing and redistributes electronic density, creating a favorable host for high\u2010voltage PF\n                    <jats:sub>6<\/jats:sub>\n                    <jats:sup>\u2212<\/jats:sup>\n                    intercalation. This synergistic activation enables an average transfer of 2.61 electrons per redox event, breaking the intrinsic one\u2010electron limit of graphite. As a result, the cathode delivers up to 5\u00a0V (vs. Na\/Na\n                    <jats:sup>+<\/jats:sup>\n                    ) with a stable capacity of 52 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    at 3 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    , significantly outperforming conventional graphite cathodes (15 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    ). By integrating multi\u2010electron redox chemistry with anion storage, this approach unlocks a new direction for high\u2010power electrochemical energy storage.\n                  <\/jats:p>","DOI":"10.1002\/anie.5529195","type":"journal-article","created":{"date-parts":[[2026,5,4]],"date-time":"2026-05-04T11:57:26Z","timestamp":1777895846000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Pre\u2010Activated Cascade Redox Enables High\u2010Voltage Multi\u2010Electron Anion Storage in Graphite"],"prefix":"10.1002","volume":"65","author":[{"given":"Zhiqin","family":"Sun","sequence":"first","affiliation":[{"name":"State Key Laboratory of Advanced Chemical Power Sources Frontiers Science Center For New Organic Matter, Academy for Advanced Interdisciplinary Studies, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Collaborative Innovation Center of Chemical Science and Engineering 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