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Herein, we developed a dual\u2010induced confined synthesis strategy that couples hydrophobic gating with thermally triggered phase transformation to precisely confine UMONs within the pores of a metal\u2013organic framework (MOF). 13 UMONs@MOF composites were successfully synthesized with the metal cations in UMONs spanning different regions of the periodic table. Notably, sub\u20103\u00a0nm metastable \u03b3\u2010MnO\n                    <jats:sub>2<\/jats:sub>\n                    was stabilized and confined within MIL\u2010101(Fe) for the first time. The optimized 15% \u03b3\u2010MnO\n                    <jats:sub>2<\/jats:sub>\n                    @MIL\u2010101(Fe) showed a durable 100% O\n                    <jats:sub>3<\/jats:sub>\n                    removal efficiency for over 100\u00a0h. This performance was maintained in a continuous air flow containing 40\u00a0ppm O\n                    <jats:sub>3<\/jats:sub>\n                    at a high gas hourly space velocity of 1.7\u00a0\u00d7\u00a010\n                    <jats:sup>5<\/jats:sup>\n                    \u00a0h\n                    <jats:sup>\u22121<\/jats:sup>\n                    over a wide humidity range of 10%\u201390%. Mechanistic studies reveal that its superior catalytic activity originates from the synergistic effect between the confined \u03b3\u2010MnO\n                    <jats:sub>2<\/jats:sub>\n                    active sites and the Fe\n                    <jats:sub>3<\/jats:sub>\n                    O clusters in the MIL\u2010101(Fe). This work provides a universal approach for the precise control of the size and crystal phase of UMONs, paving the way for designing high\u2010performance catalysts.\n                  <\/jats:p>","DOI":"10.1002\/anie.5562966","type":"journal-article","created":{"date-parts":[[2026,1,10]],"date-time":"2026-01-10T13:57:38Z","timestamp":1768053458000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":8,"title":["Dual\u2010Induced Confined Synthesis of Metastable \u03b3\u2010MnO\n                    <sub>2<\/sub>\n                    Nanoclusters in Metal\u2013Organic Frameworks for Highly Efficient Ozone Decomposition"],"prefix":"10.1002","volume":"65","author":[{"given":"Yuning","family":"Lou","sequence":"first","affiliation":[{"name":"College of Chemistry Liaoning University  Shenyang Liaoning 110036 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University  Shenyang Liaoning 110036 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lin","family":"Liu","sequence":"additional","affiliation":[{"name":"College of Chemistry Liaoning University  Shenyang Liaoning 110036 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3116-756X","authenticated-orcid":false,"given":"Zhi\u2010Ming","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute for New Energy Materials and Low Carbon Technologies, School of Materials Science and Engineering Tianjin University of Technology  Tianjin 300384 China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8635-9783","authenticated-orcid":false,"given":"Zhengbo","family":"Han","sequence":"additional","affiliation":[{"name":"College of Chemistry Liaoning University  Shenyang Liaoning 110036 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