{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T08:06:03Z","timestamp":1789977963257,"version":"4.0.1"},"reference-count":75,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T00:00:00Z","timestamp":1789948800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T00:00:00Z","timestamp":1789948800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22021001"],"award-info":[{"award-number":["22021001"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22179112"],"award-info":[{"award-number":["22179112"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    High\u2010voltage LiCoO\n                    <jats:sub>2<\/jats:sub>\n                    (LCO) is promising for high\u2010energy lithium metal batteries, yet raising charge cut\u2010off voltage above 4.5\u00a0V is essential to fully unlocking its high\u2010specific\u2010energy potential. However, deep delithiation triggers irreversible phase transitions and detrimental interfacial side reactions that originate from intrinsically vulnerable LCO surface. Herein, we propose the surface\u2010bonded molecular integration (SMI) paradigm to reconstruct LCO surface through multi\u2010site interactions, endowing it with exceptional electrochemical activity and structural robustness. A rational optimization scheme identifies mono\u2010lithiated creatinol phosphate (CPLi) as the optimal molecule. Driven by Lewis acid\u2010base interactions, CPLi precisely anchors onto coordinatively unsaturated Co\n                    <jats:sup>3+<\/jats:sup>\n                    sites through phosphate O and guanidine N, forming a chemically bonded, structurally dense interfacial integration featuring Co\u2212O\u2212P and Co\u2212N linkages. Unique spatial configuration and modulated electronic structure of surface\u2010bonded CPLi ensure rapid Li\n                    <jats:sup>+<\/jats:sup>\n                    transport and desirable cathode electrolyte interphase. Consequently, Li||LCO\u2010CPLi cells deliver outstanding durability and reversibility at 4.6\u00a0V, retaining 84.5% capacity after 1000 cycles (2 C), with 85.6% capacity recovery upon switching back to 0.2 C following 2000 cycles (2 C). Encouragingly, \u223c100 mAh g\n                    <jats:sup>\u22121<\/jats:sup>\n                    is sustained after 2800 cycles (2 C) and 2500 cycles (10 C), underscoring superior cycling longevity. Collectively, SMI\u2010paradigm provides fresh insights for advanced interfacial engineering of high\u2010voltage cathodes.\n                  <\/jats:p>","DOI":"10.1002\/anie.5600863","type":"journal-article","created":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T07:30:17Z","timestamp":1789975817000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Beyond Physical Protection Paradigm: Surface\u2010bonded Molecular Integration for Durable High\u2010voltage LiCoO\n                    <sub>2<\/sub>"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0003-5983-0658","authenticated-orcid":false,"given":"Tian","family":"Xie","sequence":"first","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces Engineering Research Centre of Electrochemical Technologies of Ministry of Education Collaborative Innovation Center of Chemistry for Energy Materials (i\u2010ChEM) Department of Chemistry College of Chemistry and Chemical Engineering Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University  Xiamen P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wenxin","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory for Polymeric Composite and Functional Materials of Ministry of Education College of Chemistry Sun Yat\u2010sen University  Guangzhou P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiancong","family":"Cheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces Engineering Research Centre of Electrochemical Technologies of Ministry of Education Collaborative Innovation Center of Chemistry for Energy Materials (i\u2010ChEM) Department of Chemistry College of Chemistry and Chemical Engineering Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University  Xiamen P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yidi","family":"Jiang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials College of Materials Xiamen University Xiamen P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruming","family":"Yuan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces Engineering Research Centre of Electrochemical Technologies of Ministry of Education Collaborative Innovation Center of Chemistry for Energy Materials (i\u2010ChEM) Department of Chemistry College of Chemistry and Chemical Engineering Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University  Xiamen P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jingmin","family":"Fan","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces Engineering Research Centre of Electrochemical Technologies of Ministry of Education Collaborative Innovation Center of Chemistry for Energy Materials (i\u2010ChEM) Department of Chemistry College of Chemistry and Chemical Engineering Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University  Xiamen P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4155-4766","authenticated-orcid":false,"given":"Dongliang","family":"Peng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces Fujian Key Laboratory of Surface and Interface Engineering for High Performance Materials College of Materials Xiamen University Xiamen P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9302-4631","authenticated-orcid":false,"given":"Mingsen","family":"Zheng","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces Engineering Research Centre of Electrochemical Technologies of Ministry of Education Collaborative Innovation Center of Chemistry for Energy Materials (i\u2010ChEM) Department of Chemistry College of Chemistry and Chemical Engineering Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University  Xiamen P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4886-3361","authenticated-orcid":false,"given":"Quanfeng","family":"Dong","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Physical Chemistry of Solid Surfaces Engineering Research Centre of Electrochemical Technologies of Ministry of Education Collaborative Innovation Center of Chemistry for Energy Materials (i\u2010ChEM) Department of Chemistry College of Chemistry and Chemical Engineering Innovation Laboratory for Sciences and Technologies of Energy Materials of Fujian Province (IKKEM) Xiamen University  Xiamen P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,9,21]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570\u2010026\u201000801\u20102"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41570\u2010023\u201000557\u2010z"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010026\u201002152\u2010x"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202520479"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010019\u20100513\u20100"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.mattod.2020.10.028"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010026\u201072486\u20106"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1021\/ja3091438"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010020\u20100567\u2010z"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1039\/C8CS00322J"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201065256\u20103"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41578\u2010022\u201000416\u20101"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41565\u2010025\u201002110\u2010z"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202523570"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2025.102166"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.adx5020"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202307404"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE01209C"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010020\u201000764\u20108"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4CS00797B"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.nanoen.2024.109537"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202521637"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1093\/nsr\/nwaf345"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/smll.202514364"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.73065"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202402223"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202408875"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202201549"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1007\/s40820\u2010023\u201001269\u20101"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1002\/elt2.33"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010024\u201001639\u2010y"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202303498"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202504221"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2025.104376"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c01128"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.5c06237"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202004664"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202001974"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2025.104081"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE03027C"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202417076"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1002\/jcc.22885"},{"key":"e_1_2_8_44_1","doi-asserted-by":"publisher","DOI":"10.1063\/5.0216272"},{"key":"e_1_2_8_45_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41560\u2010019\u20100409\u2010z"},{"key":"e_1_2_8_46_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE04240B"},{"key":"e_1_2_8_47_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202416338"},{"key":"e_1_2_8_48_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202503618"},{"key":"e_1_2_8_49_1","doi-asserted-by":"publisher","DOI":"10.1039\/D4EE02049A"},{"key":"e_1_2_8_50_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202101864"},{"key":"e_1_2_8_51_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202503100"},{"key":"e_1_2_8_52_1","doi-asserted-by":"publisher","DOI":"10.1002\/smsc.202400162"},{"key":"e_1_2_8_53_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.4c02796"},{"key":"e_1_2_8_54_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202401123"},{"key":"e_1_2_8_55_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202518546"},{"key":"e_1_2_8_56_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2025.101846"},{"key":"e_1_2_8_57_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202408152"},{"key":"e_1_2_8_58_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsenergylett.2c01433"},{"key":"e_1_2_8_59_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202512300"},{"key":"e_1_2_8_60_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.4c17362"},{"key":"e_1_2_8_61_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202425535"},{"key":"e_1_2_8_62_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202405911"},{"key":"e_1_2_8_63_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202500577"},{"key":"e_1_2_8_64_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201064396\u2010w"},{"key":"e_1_2_8_65_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.jechem.2025.02.031"},{"key":"e_1_2_8_66_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202501509"},{"key":"e_1_2_8_67_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202206405"},{"key":"e_1_2_8_68_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.joule.2024.05.008"},{"key":"e_1_2_8_69_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.202410843"},{"key":"e_1_2_8_70_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.ensm.2026.105061"},{"key":"e_1_2_8_71_1","doi-asserted-by":"publisher","DOI":"10.1002\/adma.202506228"},{"key":"e_1_2_8_72_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202424353"},{"key":"e_1_2_8_73_1","doi-asserted-by":"publisher","DOI":"10.1039\/D5EE03465E"},{"key":"e_1_2_8_74_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201059955\u20100"},{"key":"e_1_2_8_75_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3EE03464J"},{"key":"e_1_2_8_76_1","doi-asserted-by":"publisher","DOI":"10.1002\/aenm.202200197"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.5600863","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.5600863","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.5600863","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T07:30:19Z","timestamp":1789975819000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.5600863"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,9,21]]},"references-count":75,"alternative-id":["10.1002\/anie.5600863"],"URL":"https:\/\/doi.org\/10.1002\/anie.5600863","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,9,21]]},"assertion":[{"value":"2026-07-15","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-14","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-09-21","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e5600863"}}