{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T14:57:03Z","timestamp":1791212223437,"version":"4.1.0"},"reference-count":32,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/creativecommons.org\/licenses\/by\/4.0\/"},{"start":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T00:00:00Z","timestamp":1791158400000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100004281","name":"Narodowe Centrum Nauki","doi-asserted-by":"publisher","award":["2024\/53\/B\/ST5\/03275"],"award-info":[{"award-number":["2024\/53\/B\/ST5\/03275"]}],"id":[{"id":"10.13039\/501100004281","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    The recently discovered twist\u2010bend nematic N\n                    <jats:sub>TB<\/jats:sub>\n                    and ferroelectric nematic N\n                    <jats:sub>F<\/jats:sub>\n                    phases are distinct examples of spontaneous symmetry breaking in liquid crystals. Here, we report the occurrence of both type nematic phases within the same homologous series of dimers consisting of two strongly dipolar mesogenic units linked by a flexible spacer. The N\n                    <jats:sub>F<\/jats:sub>\n                    phase, observed for dimers having spacer with even number of atoms, exhibits the strong polar order; in the N\n                    <jats:sub>TB<\/jats:sub>\n                    phase, observed for dimers with odd number of atoms in the spacer, short\u2010pitch heliconical director structure develops.\n                  <\/jats:p>","DOI":"10.1002\/anie.5707650","type":"journal-article","created":{"date-parts":[[2026,10,5]],"date-time":"2026-10-05T14:40:16Z","timestamp":1791211216000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Mirror versus Inversion Symmetry Breaking in Mesogenic Dimers: N\n                    <sub>TB<\/sub>\n                    versus N\n                    <sub>F<\/sub>\n                    Phase"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0009-0000-9071-846X","authenticated-orcid":false,"given":"Ma\u0142gorzata","family":"Bakiera","sequence":"first","affiliation":[{"name":"Faculty of Advanced Technology and Chemistry Military University of Technology  Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4783-0469","authenticated-orcid":false,"given":"Jakub","family":"Karcz","sequence":"additional","affiliation":[{"name":"Faculty of Advanced Technology and Chemistry Military University of Technology  Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7734-3181","authenticated-orcid":false,"given":"Damian","family":"Pociecha","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry University of Warsaw  Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Katarzyna","family":"Kwiatkowska","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry University of Warsaw  Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Mateusz","family":"Pawlak","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry University of Warsaw  Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7862-7968","authenticated-orcid":false,"given":"Przemys\u0142aw","family":"Kula","sequence":"additional","affiliation":[{"name":"Faculty of Advanced Technology and Chemistry Military University of Technology  Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8076-5489","authenticated-orcid":false,"given":"Ewa","family":"Gorecka","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry University of Warsaw  Warsaw 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