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Although high\u2010concentration electrolytes can tune solvation structure and enhance Zn plating\/stripping stability, they suffer from high cost and low practicality. Herein, we propose a localized supersaturated electrolyte interface (LSEI) concept via constructing a low Si\/Al ratio ZSM\u20105 zeolite (LZ5) interphase on the Zn surface. The abundant Br\u00f8nsted acid sites inside the LZ5 nanochannels function as \u201cion tentacles\u201d to spontaneously capture and confine Zn\n                    <jats:sup>2+<\/jats:sup>\n                    , dramatically raising the localized Zn\n                    <jats:sup>2+<\/jats:sup>\n                    concentration on the Zn surface even in a dilute ZnSO\n                    <jats:sub>4<\/jats:sub>\n                    electrolyte (1\u00a0M). This LSEI creates a H\n                    <jats:sub>2<\/jats:sub>\n                    O\u2010deficient and anion\u2010enriched Zn\n                    <jats:sup>2+<\/jats:sup>\n                    solvation structure at the LZ5 interface, which concurrently accelerates Zn\n                    <jats:sup>2+<\/jats:sup>\n                    desolvation and transport dynamics for dendrite\u2010free deposition and suppresses H\n                    <jats:sub>2<\/jats:sub>\n                    O\u2010induced side reactions. Consequently, the LZ5@Zn symmetric cells deliver a lifespan of over 2400\u00a0h and a high cumulative capacity exceeding 5.5 Ah cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . The assembled LZ5@Zn\/\/NH\n                    <jats:sub>4<\/jats:sub>\n                    V\n                    <jats:sub>4<\/jats:sub>\n                    O\n                    <jats:sub>10<\/jats:sub>\n                    full cells achieve 96% capacity retention over 1200 cycles at 3 A g\n                    <jats:sup>\u22121<\/jats:sup>\n                    . Our findings highlight the potential of LSEI design for developing durable Zn anodes toward practical AZIBs.\n                  <\/jats:p>","DOI":"10.1002\/anie.5744163","type":"journal-article","created":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T13:26:58Z","timestamp":1789478818000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Stabilizing Zinc Anodes via a Zeolite\u2010Induced Localized Supersaturated Electrolyte Interface"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3317-4627","authenticated-orcid":false,"given":"Xiaoqi","family":"Liu","sequence":"first","affiliation":[{"name":"State Key Laboratory of Heavy Oil Processing School of Chemistry and Chemical Engineering China University of Petroleum  Qingdao Shandong China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yipu","family":"Xu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of 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