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In this study, we report a manganese\u2010based single\u2010atom photocatalyst (Mn@f\u2010g\u2010C\n                    <jats:sub>3<\/jats:sub>\n                    N\n                    <jats:sub>4<\/jats:sub>\n                    ) comprising atomically dispersed Mn\u2500N\n                    <jats:sub>x<\/jats:sub>\n                    sites anchored on an arylamino\u2010functionalised graphitic carbon nitride support. Band\u2010gap engineering was used to enhance visible\u2010light absorption to afford a robust and recyclable photocatalyst for selective visible\u2010light\u2010driven C(sp\n                    <jats:sup>2<\/jats:sup>\n                    )\u2500H chlorination of arenes and heteroarenes under mild conditions. Mechanistic investigations support a dual\u2010site pathway initiated at the carbon nitride support and continued at the Mn centre. Photoexcitation of the carbon nitride support triggers single\u2010electron transfer to the N\u2010chlorosuccinimide chlorination reagent, generating reactive Cl species, leading to the formation of well\u2010defined Mn\u2500Cl intermediates. Chlorine transfer to the arene substrate is mediated via a cyclohexadienyl radical intermediate, followed by oxidation and deprotonation, affording the chlorinated product. Cooperation between the Mn atom and support suppresses unselective free\u2010radical chlorination pathways and enforces surface\u2010confined selectivity.\n                  <\/jats:p>","DOI":"10.1002\/anie.5772245","type":"journal-article","created":{"date-parts":[[2026,9,27]],"date-time":"2026-09-27T06:18:33Z","timestamp":1790489913000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Interfacial Mn\u2010Carbon Nitride Synergy Enables Selective Photocatalytic C\u2500H Chlorination via Single\u2010Atom Catalysis"],"prefix":"10.1002","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9517-748X","authenticated-orcid":false,"given":"Jaro","family":"Vanderghinste","sequence":"first","affiliation":[{"name":"Department of Chemistry University of Antwerp  Antwerp Belgium"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3161-1547","authenticated-orcid":false,"given":"Prakash 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