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Conventional removal strategies such as physical adsorption and catalytic degradation often suffer from low efficiency, secondary CO\n                    <jats:sub>2<\/jats:sub>\n                    emission, or high energy consumption. Herein, we report a novel formaldehyde\u2010ozone battery by coupling anodic HCHO oxidation with cathodic O\n                    <jats:sub>3<\/jats:sub>\n                    reduction reactions, which simultaneously enables the efficient detoxification of hazardous wastes and electricity generation. With nitrogen\u2010doped carbon and CuAg composites as the cathodic and anodic catalysts, the as\u2010fabricated formaldehyde\u2010ozone battery delivers a considerably high open\u2010circuit voltage (OCV) of 1.80\u00a0V and a large peak power density of 44.3\u00a0mW cm\n                    <jats:sup>\u22122<\/jats:sup>\n                    . Even in simulated waste streams, a large\u2010scale formaldehyde\u2010ozone battery (25 cm\n                    <jats:sup>2<\/jats:sup>\n                    ) achieves conversions of 99.1% HCHO and 99.97% O\n                    <jats:sub>3<\/jats:sub>\n                    . Therefore, this work provides a sustainable and efficient strategy for the removal of HCHO and O\n                    <jats:sub>3<\/jats:sub>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/anie.5881961","type":"journal-article","created":{"date-parts":[[2026,8,31]],"date-time":"2026-08-31T04:57:47Z","timestamp":1788152267000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Formaldehyde\u2010Ozone Battery for the Detoxification of Hazardous Wastes and Electricity Generation"],"prefix":"10.1002","volume":"65","author":[{"given":"Siying","family":"An","sequence":"first","affiliation":[{"name":"State Key Laboratory of Solidification Processing and School of Materials Science and Engineering Northwestern Polytechnical University  Xi'an Shaanxi P. R. China"},{"name":"CNPC Tubular Goods Research Institute State Key Laboratory of Petroleum Tubular Goods and Equipment Quality Safety State Administration for Market Regulation  Xi'an Shaanxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Linjia","family":"Li","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solidification Processing and School of Materials Science and Engineering Northwestern Polytechnical University  Xi'an Shaanxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jiaxin","family":"He","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solidification Processing and School of Materials Science and Engineering Northwestern Polytechnical University  Xi'an Shaanxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0004-2840-6042","authenticated-orcid":false,"given":"Rui","family":"Bai","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solidification Processing and School of Materials Science and Engineering Northwestern Polytechnical University  Xi'an Shaanxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jin","family":"Lin","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solidification Processing and School of Materials Science and Engineering Northwestern Polytechnical University  Xi'an Shaanxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Chang","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solidification Processing and School of Materials Science and Engineering Northwestern Polytechnical University  Xi'an Shaanxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0640-4033","authenticated-orcid":false,"given":"Zhenpeng","family":"Liu","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solidification Processing and School of Materials Science and Engineering Northwestern Polytechnical University  Xi'an Shaanxi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0912-1197","authenticated-orcid":false,"given":"Jian","family":"Zhang","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Solidification Processing and School of Materials Science and Engineering Northwestern Polytechnical University  Xi'an Shaanxi P. R. 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