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While the previously reported crystal structure of tris(\n                    <jats:italic>p\u2010<\/jats:italic>\n                    tolyl)antimony(III) is known to exhibit phenyl embrace motifs, resembling the arsenic or phosphorus analogs, the new polymorph exhibits supramolecular dimers characterized by direct Sb\u2219\u2219\u2219Sb contacts shorter than the sum of the van der Waals radii, and stabilized by a significant dimer dissociation energy of ca. \u221226\u00a0kJ mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    established by periodic density\u2010functional calculations. Theoretical analysis indicates that the contacts are attractive and dispersion\u2010dominated, with an overview of the CSD showing that such direct Sb\u00b7\u00b7\u00b7Sb contacts are not unique to this polymorphic form of tris(\n                    <jats:italic>p\u2010<\/jats:italic>\n                    tolyl)antimony(III) but appear to be a more general feature of trivalent organoantimony in the solid state. Specifically, the CSD shows that dimers based on short Sb\u00b7\u00b7\u00b7Sb contacts are found across a number of organoantimony structures, including some of the simplest representatives of the series, such as triphenyl\u2010 and trimethylantimony, for which the dimer interaction energy is herein calculated to be ca. \u221213\u00a0kJ mol\n                    <jats:sup>\u22121<\/jats:sup>\n                    .\n                  <\/jats:p>","DOI":"10.1002\/anie.5894899","type":"journal-article","created":{"date-parts":[[2026,8,12]],"date-time":"2026-08-12T16:42:15Z","timestamp":1786552935000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Short Sb\u00b7\u00b7\u00b7Sb Contacts in Polymorphic Tris(\n                    <i>p\u2010<\/i>\n                    Tolyl)Antimony: A Hallmark of Organoantimony(III) Solid\u2010State Chemistry?"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0009-0001-0955-7433","authenticated-orcid":false,"given":"Imogen","family":"Suh","sequence":"first","affiliation":[{"name":"Department of Chemistry McGill University  Montreal Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5479-1878","authenticated-orcid":false,"given":"Michael","family":"Ferguson","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Birmingham  Edgbaston UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3811-6036","authenticated-orcid":false,"given":"Filip","family":"Topi\u0107","sequence":"additional","affiliation":[{"name":"Department of Chemistry McGill University  Montreal Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0008-7688-0901","authenticated-orcid":false,"given":"Fu\u2010Qiang","family":"Gong","sequence":"additional","affiliation":[{"name":"School of Chemistry University of Birmingham  Edgbaston UK"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1150-3108","authenticated-orcid":false,"given":"Mihails","family":"Arhangelskis","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry University of Warsaw  Warsaw Poland"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0654-1292","authenticated-orcid":false,"given":"Hatem M.","family":"Titi","sequence":"additional","affiliation":[{"name":"Department of Chemistry McGill University  Montreal Canada"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5833-5696","authenticated-orcid":false,"given":"D. 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