{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T15:07:29Z","timestamp":1790003249832,"version":"4.0.1"},"reference-count":42,"publisher":"Wiley","issue":"39","license":[{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T00:00:00Z","timestamp":1784764800000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22561038"],"award-info":[{"award-number":["22561038"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004772","name":"Natural Science Foundation of Ningxia Province","doi-asserted-by":"publisher","award":["2025AAC030137"],"award-info":[{"award-number":["2025AAC030137"]}],"id":[{"id":"10.13039\/501100004772","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100004772","name":"Natural Science Foundation of Ningxia Province","doi-asserted-by":"publisher","award":["2024AAC03032"],"award-info":[{"award-number":["2024AAC03032"]}],"id":[{"id":"10.13039\/501100004772","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100016692","name":"Key Research and Development Program of Ningxia","doi-asserted-by":"publisher","award":["2025BEH04001"],"award-info":[{"award-number":["2025BEH04001"]}],"id":[{"id":"10.13039\/100016692","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"published-print":{"date-parts":[[2026,9,21]]},"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Luminescent coinage metal clusters (CMCs) hold great promise for bioimaging and optical applications, but long\u2010lived room\u2010temperature phosphorescence (RTP) with high quantum yield remains challenging. Herein, a F\u00f6rster resonance energy transfer (FRET) glue strategy using Ag\n                    <jats:sup>+<\/jats:sup>\n                    to bridge donor\u2013acceptor (D\/A) pairs is adopted to synthesize a series of clusters in CH\n                    <jats:sub>3<\/jats:sub>\n                    CN (\n                    <jats:bold>\n                      Ag\n                      <jats:sub>4<\/jats:sub>\n                    <\/jats:bold>\n                    ), CH\n                    <jats:sub>3<\/jats:sub>\n                    OH [\n                    <jats:bold>\n                      Ag\n                      <jats:sub>4<\/jats:sub>\n                      (CH\n                      <jats:sub>3<\/jats:sub>\n                      OH)\n                      <jats:sub>2<\/jats:sub>\n                    <\/jats:bold>\n                    ], C\n                    <jats:sub>2<\/jats:sub>\n                    H\n                    <jats:sub>5<\/jats:sub>\n                    OH [\n                    <jats:bold>\n                      Ag\n                      <jats:sub>4<\/jats:sub>\n                      (C\n                      <jats:sub>2<\/jats:sub>\n                      H\n                      <jats:sub>5<\/jats:sub>\n                      OH)\n                    <\/jats:bold>\n                    ], and\n                    <jats:italic>i<\/jats:italic>\n                    \u2010C\n                    <jats:sub>3<\/jats:sub>\n                    H\n                    <jats:sub>7<\/jats:sub>\n                    OH [\n                    <jats:bold>\n                      Ag\n                      <jats:sub>2<\/jats:sub>\n                      (\n                      <jats:italic>i<\/jats:italic>\n                      \u2010C\n                      <jats:sub>3<\/jats:sub>\n                      H\n                      <jats:sub>7<\/jats:sub>\n                      OH)\n                      <jats:sub>2<\/jats:sub>\n                    <\/jats:bold>\n                    ] realizing near\u2010unity FRET efficiency. Among them,\n                    <jats:bold>\n                      Ag\n                      <jats:sub>4<\/jats:sub>\n                      (CH\n                      <jats:sub>3<\/jats:sub>\n                      OH)\n                      <jats:sub>2<\/jats:sub>\n                    <\/jats:bold>\n                    delivers superior thermally activated delayed phosphorescence with a high photoluminescence quantum yield of 96% and an ultralong RTP lifetime of around 100\u00a0ms, which are 5.6 times and 400 times higher than those of\n                    <jats:bold>\n                      Ag\n                      <jats:sub>4<\/jats:sub>\n                    <\/jats:bold>\n                    , respectively. Mechanistic studies reveal that isolated Ag\n                    <jats:sup>+<\/jats:sup>\n                    as single\u2010point linkers circumvent the overly strong spin\u2013orbit coupling of larger Ag cores while retaining an appropriate heavy\u2010atom effect to facilitate effective phosphorescence emission. In addition, hydrogen bonds from coordinating solvents can adjust the spatial position of ligand, optimizing D\/A arrangement, which enhances FRET efficiency and suppresses nonradiative deactivation, ultimately achieving high\u2010efficiency luminescence of silver clusters. Leveraging the solvent\u2010mediated regulation of cluster structure and performance, this system enables reversible single\u2010crystal\u2010to\u2010single\u2010crystal transformation and subsequent time\u2010solvent\u2010temperature\u2010gated multilevel information encryption. This work provides a general design principle for CMCs with high\u2010performance RTP.\n                  <\/jats:p>","DOI":"10.1002\/anie.5966275","type":"journal-article","created":{"date-parts":[[2026,7,23]],"date-time":"2026-07-23T10:09:49Z","timestamp":1784801389000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["A Hydrogen Bond\u2010Mediated F\u00f6rster Resonance Energy Transfer (FRET) Glue Strategy for Long\u2010Lived Room\u2010Temperature Phosphorescence From Silver Clusters"],"prefix":"10.1002","volume":"65","author":[{"given":"Qiang\u2010Qiang","family":"Chai","sequence":"first","affiliation":[{"name":"School of Materials and New Energy Ningxia University  Yinchuan Ningxia China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0009-0007-9384-7364","authenticated-orcid":false,"given":"Shuai\u2010Qi","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Materials and New Energy Ningxia University  Yinchuan Ningxia China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jian\u2010Yu","family":"Wei","sequence":"additional","affiliation":[{"name":"School of Materials and New Energy Ningxia University  Yinchuan Ningxia China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Wen\u2010Ya","family":"Jiang","sequence":"additional","affiliation":[{"name":"School of Materials and New Energy Ningxia University  Yinchuan Ningxia China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jing\u2010Zhe","family":"Li","sequence":"additional","affiliation":[{"name":"School of Materials and New Energy Ningxia University  Yinchuan Ningxia China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3900-563X","authenticated-orcid":false,"given":"Zhenghuan","family":"Lin","sequence":"additional","affiliation":[{"name":"College of Chemistry and Materials Science Fujian Normal University  Fuzhou Fujian China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiao\u2010Yan","family":"Huang","sequence":"additional","affiliation":[{"name":"School of Materials and New Energy Ningxia University  Yinchuan Ningxia China"},{"name":"School of Chemistry and Chemical Engineering Ningxia University  Yinchuan Ningxia China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Kuan\u2010Guan","family":"Liu","sequence":"additional","affiliation":[{"name":"School of Materials and New Energy Ningxia University  Yinchuan Ningxia China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"311","published-online":{"date-parts":[[2026,7,23]]},"reference":[{"key":"e_1_2_8_2_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adk6628"},{"key":"e_1_2_8_3_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202421656"},{"key":"e_1_2_8_4_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.6076409"},{"key":"e_1_2_8_5_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adh2365"},{"key":"e_1_2_8_6_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c21644"},{"key":"e_1_2_8_7_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.2c06093"},{"key":"e_1_2_8_8_1","doi-asserted-by":"publisher","DOI":"10.1126\/science.adx6639"},{"key":"e_1_2_8_9_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202407518"},{"key":"e_1_2_8_10_1","doi-asserted-by":"publisher","DOI":"10.1021\/acsnano.4c16160"},{"key":"e_1_2_8_11_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201065024\u20103"},{"key":"e_1_2_8_12_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202515551"},{"key":"e_1_2_8_13_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202101141"},{"key":"e_1_2_8_14_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201057209\u20107"},{"key":"e_1_2_8_15_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.jpclett.4c03544"},{"key":"e_1_2_8_16_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.5c01348"},{"key":"e_1_2_8_17_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201062232\u20109"},{"key":"e_1_2_8_18_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202423787"},{"key":"e_1_2_8_19_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202507412"},{"key":"e_1_2_8_20_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202508578"},{"key":"e_1_2_8_21_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202104391"},{"key":"e_1_2_8_22_1","doi-asserted-by":"publisher","DOI":"10.1021\/prechem.4c00044"},{"key":"e_1_2_8_23_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202518269"},{"key":"e_1_2_8_24_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202521059"},{"key":"e_1_2_8_25_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202404798"},{"key":"e_1_2_8_26_1","doi-asserted-by":"publisher","DOI":"10.1126\/sciadv.aay0107"},{"key":"e_1_2_8_27_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.3c02292"},{"key":"e_1_2_8_28_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010024\u201049735\u20107"},{"key":"e_1_2_8_29_1","doi-asserted-by":"publisher","DOI":"10.1039\/c2cc36169h"},{"key":"e_1_2_8_30_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202506509"},{"key":"e_1_2_8_31_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2024.148860"},{"key":"e_1_2_8_32_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.1c11208"},{"key":"e_1_2_8_33_1","doi-asserted-by":"publisher","DOI":"10.1021\/acs.inorgchem.1c02867"},{"key":"e_1_2_8_34_1","doi-asserted-by":"publisher","DOI":"10.1039\/C0CC04391E"},{"key":"e_1_2_8_35_1","doi-asserted-by":"publisher","DOI":"10.1039\/D3NR00571B"},{"key":"e_1_2_8_36_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202424499"},{"key":"e_1_2_8_37_1","doi-asserted-by":"publisher","DOI":"10.1021\/jacs.0c06682"},{"key":"e_1_2_8_38_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010018\u201004499\u20109"},{"key":"e_1_2_8_39_1","doi-asserted-by":"publisher","DOI":"10.1063\/1.2762283"},{"key":"e_1_2_8_40_1","doi-asserted-by":"publisher","DOI":"10.1002\/adfm.201807599"},{"key":"e_1_2_8_41_1","doi-asserted-by":"publisher","DOI":"10.1038\/s41467\u2010025\u201067834\u2010x"},{"key":"e_1_2_8_42_1","doi-asserted-by":"publisher","DOI":"10.1002\/anie.202400742"},{"key":"e_1_2_8_43_1","doi-asserted-by":"publisher","DOI":"10.1016\/j.cej.2025.171577"}],"container-title":["Angewandte Chemie International Edition"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.5966275","content-type":"application\/pdf","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/full-xml\/10.1002\/anie.5966275","content-type":"application\/xml","content-version":"vor","intended-application":"text-mining"},{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/pdf\/10.1002\/anie.5966275","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T14:40:43Z","timestamp":1790001643000},"score":1,"resource":{"primary":{"URL":"https:\/\/onlinelibrary.wiley.com\/doi\/10.1002\/anie.5966275"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2026,7,23]]},"references-count":42,"journal-issue":{"issue":"39","published-print":{"date-parts":[[2026,9,21]]}},"alternative-id":["10.1002\/anie.5966275"],"URL":"https:\/\/doi.org\/10.1002\/anie.5966275","archive":["Portico"],"relation":{},"ISSN":["1433-7851","1521-3773"],"issn-type":[{"value":"1433-7851","type":"print"},{"value":"1521-3773","type":"electronic"}],"subject":[],"published":{"date-parts":[[2026,7,23]]},"assertion":[{"value":"2026-05-31","order":0,"name":"received","label":"Received","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-09","order":2,"name":"accepted","label":"Accepted","group":{"name":"publication_history","label":"Publication History"}},{"value":"2026-07-23","order":3,"name":"published","label":"Published","group":{"name":"publication_history","label":"Publication History"}}],"article-number":"e5966275"}}