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Current approaches using porous inorganic materials to physically trap polyiodide species or organic additives to electrostatically bind them remain ineffective due to size mismatches or weak ionic interactions. Here, we introduce a host\u2010guest strategy to cage polyhalides while enabling their transport between niches within a cross\u2010linked polycyclodextrin (polyCD) network. Experimental and computational results indicate that the polymer derived from \u03b2\u2010CD exhibits a moderate binding affinity to polyhalide anions, attributable to its appropriate inner diameter and hydrophobic cavity. For our poly(\u03b2\u2010CD)\/KI\n                    <jats:sub>3<\/jats:sub>\n                    cathode, the addition of Br\n                    <jats:sup>\u2212<\/jats:sup>\n                    results in more effective binding to I\n                    <jats:sup>+<\/jats:sup>\n                    and inhibition of its hydrolysis compared to Cl\n                    <jats:sup>\u2212<\/jats:sup>\n                    . As such, AZIBs with poly(\u03b2\u2010CD)\/KI\n                    <jats:sub>3<\/jats:sub>\n                    can achieve 2e storage at 205 mAh\/g or 4e storage at 365 mAh\/g. The specific inclusion chemistry between polyhalide anions and poly(\u03b2\u2010CD) enables batteries to operate for more than 60,000 cycles, with a capacity fade of 0.0001%\u20130.0003% per cycle for 2e and 4e storage, respectively. This work offers a new approach to mitigate polyhalide shuttling by using polymers derived from inexpensive, biodegradable oligosaccharides, thereby enabling sustainable, long\u2010lasting AZIBs.\n                  <\/jats:p>","DOI":"10.1002\/anie.6010682","type":"journal-article","created":{"date-parts":[[2026,8,13]],"date-time":"2026-08-13T15:56:15Z","timestamp":1786636575000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Caging Polyhalide Anions in Polycyclodextrin for Long\u2010Lasting Aqueous Zinc\u2010Iodine Batteries"],"prefix":"10.1002","volume":"65","author":[{"ORCID":"https:\/\/orcid.org\/0009-0009-9583-9282","authenticated-orcid":false,"given":"Shangxu","family":"Jiang","sequence":"first","affiliation":[{"name":"College of Science and Engineering Flinders University  Bedford Park South Australia 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