{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T05:47:20Z","timestamp":1791870440892,"version":"4.3.4"},"reference-count":33,"publisher":"Wiley","license":[{"start":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T00:00:00Z","timestamp":1791763200000},"content-version":"vor","delay-in-days":0,"URL":"http:\/\/onlinelibrary.wiley.com\/termsAndConditions#vor"},{"start":{"date-parts":[[2026,10,12]],"date-time":"2026-10-12T00:00:00Z","timestamp":1791763200000},"content-version":"tdm","delay-in-days":0,"URL":"http:\/\/doi.wiley.com\/10.1002\/tdm_license_1.1"}],"funder":[{"DOI":"10.13039\/501100001809","name":"National Natural Science Foundation of China","doi-asserted-by":"publisher","award":["22375150"],"award-info":[{"award-number":["22375150"]}],"id":[{"id":"10.13039\/501100001809","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":["onlinelibrary.wiley.com"],"crossmark-restriction":true},"short-container-title":["Angew Chem Int Ed"],"abstract":"<jats:title>ABSTRACT<\/jats:title>\n                  <jats:p>\n                    Interfacial electronic coupling plays a decisive role in governing excited\u2010state evolution and signal transduction in optoelectronic systems, yet dynamically adaptive interfaces driven by valence\u2010state evolution remain largely unexplored in fluorescent sensing platforms. Herein, an Eu\u2010functionalized Ce\u2010MOF\/CTF heterointerface is constructed to establish a valence\u2010responsive optoelectronic system for dual\u2010mode H\n                    <jats:sub>2<\/jats:sub>\n                    O\n                    <jats:sub>2<\/jats:sub>\n                    sensing. Upon oxidative stimulation, the Ce\u2010MOF\/CTF heterointerface dynamically reconstructs the interfacial charge\u2010transfer network through Ce\n                    <jats:sup>3+<\/jats:sup>\n                    \/Ce\n                    <jats:sup>4+<\/jats:sup>\n                    valence\u2010state evolution, enabling modulation of electron migration across the interface and synchronously regulating Eu\u2010centered luminescence, CTF\u2010derived fluorescence, and nanozyme\u2010mediated catalytic outputs. The results reveal that oxidative valence evolution induces adaptive interfacial electronic redistribution and excited\u2010state pathway reconstruction, thereby amplifying microscopic electronic perturbations into programmable fluorescence\u2013catalytic responses. Beyond conventional sensing systems dominated by static emissive centers, this work demonstrates that adaptive interface states can function as dynamic optoelectronic units for intelligent signal transduction. Furthermore, the interfacial optical response can be integrated into flexible electrospun membranes and machine\u2010learning\u2010assisted visual recognition systems, enabling portable dual\u2010mode visual sensing. This work provides a new perspective for constructing adaptive optoelectronic interfaces through valence\u2010state engineering and establishes a general framework for next\u2010generation intelligent sensing platforms.\n                  <\/jats:p>","DOI":"10.1002\/anie.6056816","type":"journal-article","created":{"date-parts":[[2026,10,13]],"date-time":"2026-10-13T05:21:27Z","timestamp":1791868887000},"update-policy":"https:\/\/doi.org\/10.1002\/crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Cerium Valence\u2010Gated Interfacial Exciton Reconstruction for Fluorescence Modulation"],"prefix":"10.1002","author":[{"given":"Yin\u2010sheng","family":"Liu","sequence":"first","affiliation":[{"name":"Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering Tongji University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Rui","family":"Xue","sequence":"additional","affiliation":[{"name":"State Key Laboratory of Chemistry and Utilization of Carbon Based Energy Resources, College of Chemistry Xinjiang University  Urumqi P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Alituniguli","family":"Maimaiti","sequence":"additional","affiliation":[{"name":"Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering Tongji University  Shanghai P. R. China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0216-9454","authenticated-orcid":false,"given":"Bing","family":"Yan","sequence":"additional","affiliation":[{"name":"Shanghai Key Lab of Chemical Assessment and Sustainability, School of Chemical Science and Engineering Tongji University  Shanghai P. R. 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